catena-Poly[[(diaquacalcium)-bis(μ-2-fluorobenzoato)-1′:1κ3O:O,O′;1:1′′κ3O,O′:O] 2,2′-bipyridine hemisolvate]
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چکیده
منابع مشابه
catena-Poly[[(diaquacalcium)-bis(μ-2-fluorobenzoato)-1′:1κ3 O:O,O′;1:1′′κ3 O,O′:O] 2,2′-bipyridine hemisolvate]
In the title compound, {[Ca(C(7)H(4)FO(2))(2)(H(2)O)(2)]·0.5C(10)H(8)N(2)}(n), the Ca(II) atom is coordinated by eigth O atoms from four 2-fluoro-benzoate ligands and two water mol-ecules, resulting in a distorted CaO(8) square-anti-prismatic coordination environment. The 2-fluoro-benzoate ligand bridges two symmetry-related Ca(II) atoms, giving rise to a chain structure extending along [100]. ...
متن کاملcatena-Poly[[[diaqua(1,10-phenanthroline-κ2 N,N′)zinc]-μ-4,4′-bipyridine-κ2 N:N′] dinitrate 4,4′-bipyridine hemisolvate monohydrate]
In the title compound, [Zn(C(10)H(8)N(2))(C(12)H(8)N(2))(H(2)O)(2)](NO(3))(2)·0.5C(10)H(8)N(2)·H(2)O, the Zn(II) atom is coordinated in a distorted octa-hedral geometry by two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water mol-ecules. The 4,4'-bipy ligands bridge the Zn(II) atoms into a ch...
متن کامل{2-[2-(Carboxymethoxy)phenoxy]acetato}[2,2′-(o-phenylenedioxy)diacetic acid]sodium 4,4′-bipyridine hemisolvate monohydrate
In the title compound, [Na(C(10)H(9)O(6))(C(10)H(10)O(6))]·0.5C(10)H(8)N(2)·H(2)O, the Na atom is eight-coordinated in an distorted dicapped-octa-hedral geometry by eight O atoms from a 2-(2-carb-oxy-meth-oxy-phen-oxy)acetate (o-BDOAH) anion and a 2,2'-(o-phenyl-enedi-oxy)diacetic acid (o-BDOAH(2)) mol-ecule. The uncoordinated 4,4'-bipyridine mol-ecule is arranged around an inversion center and...
متن کامل(2,2′-Bipyridine-κ2 N,N′)[2-tert-butylanilinato(2−)]dichloridooxidomolybdenum(VI) dichloromethane hemisolvate
The Mo(VI) atom in the title structure, [Mo(C(10)H(13)N)Cl(2)O(C(10)H(8)N(2))]·0.5CH(2)Cl(2), has a distorted octa-hedral coord-ination sphere with cis-orientated oxide and imide ligands, trans-chloride ligands and the 2,2'-bipyridine (bipy) ligand N atoms lying trans to the oxide and imide ligands. An imide-ligand tert-butyl-methyl-group H atom makes a close approach with the oxide ligand (dis...
متن کاملcatena-Poly[[[tetraaquacobalt(II)]-μ-4,4′-bipyridine-κ2 N:N′] 2-[4-(2-carboxylatoethyl)phenoxy]acetate]
In the title complex, {[Co(C(10)H(8)N(2))(H(2)O)(4)](C(11)H(10)O(5))}(n), the unique Co(II) ion lies on an inversion center and is coordinated by two N atoms from two 4,4'-bipyridine ligands and four O atoms from four water mol-ecules in a slightly distorted octa-hedral coordination geometry. The 4,4'-bipyridine ligands bridge Co(II) ions into a one-dimensional chain structure. In the crystal s...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s1600536811053311