Coordination Behaviour of a Hexadentate 1,1′-Ferrocenylene-Bridged Bisphosphole towards Coinage Metal Centres
نویسندگان
چکیده
منابع مشابه
Synthesis and transition metal coordination chemistry of a novel hexadentate bispidine ligand.
Reported is the new bispidine-derived hexadentate ligand (L = 3-(2-methylpyridyl)-7-(bis-2-methylpyridyl)-3,7-diazabicyclo[3.3.1]nonane) with two tertiary amine and four pyridine donor groups. This ligand can form heterodinuclear and mononuclear complexes and, in the mononuclear compounds discussed here, the ligand may coordinate as a pentadentate ligand, with one of the bispyridinemethane-base...
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WIDEPHOS, a β-cyclodextrin cavitand bearing two introverted P(III) donor atoms, readily accommodates two converging Au-X fragments (X = Cl, Br, I). In the corresponding [(WIDEPHOS)(AuX)(2)] complexes, severe steric crowding within the cavity results in one of the P-Au-X rods deviating from linearity, as revealed by an X-ray diffraction study and unusual (31)P magnetic shielding of one of the tw...
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Magnetic water-soluble cyano-bridged metallic coordination polymer nanoparticles of controlled size were prepared by using water-soluble chitosan beads.
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Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η(2)-P4 complexes. This novel approach allows controlled P-C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.
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The M-(η2-BMn) complex [(η5-C5H5)(OC)2Mn{μ-B(Cl)(tBu)Au(PPh3)}] (2) can be functionalized via halide substitution reactions to afford isostructural complexes [(η5-C5H5)(OC)2Mn{μ-B(R)(tBu)Au(PPh3)}] (R = Ph, CCPh and NCS). It also reacts with coinage metal complexes [MCl(PPh3)] (M = Au, Ag and Cu) in the presence of halide abstraction reagents to afford borylene-bridged heteromultinuclear comple...
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ژورنال
عنوان ژورنال: European Journal of Inorganic Chemistry
سال: 2013
ISSN: 1434-1948
DOI: 10.1002/ejic.201301281