Methyl 2,2-dimethoxy-5,5-bis(methylsulfanyl)-3-oxopent-4-enedithioate
نویسنده
چکیده
In the title mol-ecule, C(10)H(16)O(3)S(4), a short intra-molecular S⋯O(=C) distance [2.726 (2) Å] indicates the presence of a nonbonding attractive inter-action. In the crystal, mol-ecules are linked into centrosymmetric dimers via weak inter-molecular C-H⋯O and S⋯S [3.405 (3) Å] inter-actions. These dimers are linked by further weak C-H⋯O inter-actions into columns along the a axis.
منابع مشابه
Bis{μ-4,4′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenolato}bis({4,4′-dimethoxy-2,2′-[propane-1,2-diylbis(nitrilomethylidyne)]diphenol}manganese(III)) bis(hexafluoridophosphate)
In the title complex, [Mn(2)(C(19)H(20)N(2)O(4))(2)(C(19)H(22)N(2)O(4))(2)](PF(6))(2), the Mn(III) ion is coordinated by two O [Mn-O = 1.855 (2) and 1.887 (2) Å] and two N [Mn-N = 1.982 (3) and 1.977 (3) Å] atoms from the tetra-dentate Schiff base ligand and a coordinated axial ligand [Mn-O = 2.129 (2) Å]. The centrosymmetric dimer contains two Jahn-Teller-distorted Mn(III) ions, each in a near...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012