Boron and nitrogen-rich carbons from ionic liquid precursors with tailorable surface properties.

نویسندگان

  • Pasquale F Fulvio
  • Je Seung Lee
  • Richard T Mayes
  • Xiqing Wang
  • Shannon M Mahurin
  • Sheng Dai
چکیده

A novel strategy for tailoring the adsorption and structural properties of ionic liquid derived carbons has been developed. By changing the carbonization temperature and ratios of ionic liquids (ILs) containing a cross-linkable anion, such as 1-butyl-3-methylimidazolium tricyanomethanide [BMIm][C(CN)(3)] and 1-ethyl-3-methylimidazolium tetracyanoborate [EMIm][B(CN)(4)], boron and nitrogen-rich carbons with slit-like pores and specific surface areas exceeding 500 m(2) g(-1) have been prepared. Furthermore, the nitrogen-rich carbons exhibit high adsorption capacity for CO(2) adsorption and selectivity for CO(2)/N(2) separation.

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عنوان ژورنال:
  • Physical chemistry chemical physics : PCCP

دوره 13 30  شماره 

صفحات  -

تاریخ انتشار 2011