A simple, accurate and sensitive spectrophotometric method was described for the determination of sulfacetamide sodium in an aqueous solution. The is based on oxidative coupling reaction N,N-diethyl-p-phenelenediamine with presence potassium dichromate as oxidizing agent acidic medium to form a violet- colored product, which has maximum absorbance at 546 nm. Beer׳s law obeyed concentration rang...

Focus of this paper is the description of common used methods for hexavalent chromium measurement. This work is focused especially on commonly available spectrophotometric method based on the reaction with 1,5-diphenylcarbazide, because not every laboratory is equipped with modern devices for this pollutant measurement,. Special attention was focused on the variability possibilities of the basi...

A cost-effective b[combining low line]a[combining low line]ttery-powered s[combining low line]pectrophotometric s[combining low line]ystem (BASS) was developed for quantitative point-of-care (POC) analysis on a microfluidic chip. By using methylene blue as a model analyte, we first compared the performance of the BASS with a commercial spectrophotometric system, and further applied the BASS for...

This paper discusses a current misinterpretation between different parameters of hemoglobin concentration measurement and its amplification under conditions of blood loss. The paper details the distinction between microcirculatory hematocrit and the hematocrit of the macrocirculation to analyze clinical use of real-time patient hemoglobin concentration measurement by noninvasive point-of-care d...

New, simple and convenient potentiometric and spectrophotometric methods are described for the determination of dextromethorphan hydrobromide (DXM) in pharmaceutical preparations. The potentiometric technique is based on developing a potentiometric sensor incorporating the dextromethorphan tetrakis(p-chlorophenyl)borate ion-pair complex as an electroactive species in a plasticized PVC matrix me...

This review explores the question whether chemometrics methods enhance the performance of electroanalytical methods. Electroanalysis has long benefited from the well-established techniques such as potentiometric titrations, polarography and voltammetry, and the more novel ones such as electronic tongues and noses, which have enlarged the scope of applications. The electroanalytical methods have...

The simultaneous determination of sulfamethoxazole (SMX) and trimethoprim (TMP) mixtures in bovine milk by spectrophotometric method is, due to spectral interferences, a difficult problem in analytical chemistry. By means of multivariate calibration methods, such as partial least square (PLS) regression, it is possible to obtain a model adjusted to the concentration values of the mixtures used ...

the present work reports a kinetic spectrophotometric method for the determination of traceamounts of sulphite that is based on inhibitory effect of sulphite on the oxidation of methyleneblue (mb) in acidic media. the reaction is followed spectrophotometrically by monitoring thedecrease in absorbance of mb at 664 nm with a fixed time of 0.5-4.5 minutes. it was found thatsulphite exert a strong ...

a simple, economical, precise and fast visible spectrophotometric method has been developed for the determination of azathioprine in tablet dosage form. developed method is based on the formation of extractable colored complex of drug with colouring agent indigo carmine and methyl orange. a wavelength maximum was found to be 683.7 nm and 566 nm. the concentration range of 15-50 μg ml-1 with of ...

A derivative UV spectrophotometric and a reversed phase high-performance liquid chromatographic method for the determination of ciprofibrate in tablets was developed. The first-order derivative UV spectrophotometric method was found to be accurate with 100.57±0.97 recovery and precise with a coefficient of variation of 1.44. These results were compared to those obtained by reference methods, ze...