Systematic studies of nanocrystalline nickel tungstate, NiWO4, thin films were performed by several experimental techniques such as Ni Kand W L1,3-edges X-ray absorption spectroscopy, X-ray diffraction, Raman spectroscopy, atomic force microscopy and cyclic voltammetry measurements. We found that the NiWO4 thin films exhibit electrochromic properties similar to that of amorphous tungsten trioxi...

A need t o find a suitable replacement for cadmium electroplated coatings on mediumto highstrength steels has accelerated the development of economically viable alternatives. This edited version of a presentation at the 30th annual AerospaceIAirline Plating & Metal Finishing Forum examines the development of Australia's Defence Science and Technology Organisation's (DSTO) zinc-nickel electropla...

We have deposited a series of WC–Co coatings by the high velocity oxy fuel (HVOF) process, using three different powders, and different spray conditions. The powders are a nanocrystalline (Nanocarb), a near-nanostructured powder (Infralloy) containing a proprietary additive aimed at retarding grain growth, and multimodal (mixed micro and nano) powder (Nanomyte). HVOF spray conditions were stoic...

Equal channel angular pressing results in ultrafine-grained (approximately 200-500 nm) Ti with superior mechanical properties without harmful alloying elements, which benefits medical implants. To further improve the bioactivity of Ti surfaces, Ca/P-containing porous titania coatings were prepared on ultrafine-grained and coarse-grained Ti by micro-arc oxidation (MAO). The phase identification,...

A method is presented to improve the tool life and cutting performance of 300mm diameter tungsten carbide (WC) micro end mills by applying thin (o300nm) fine-grained diamond (FGD) and nanocrystalline diamond (NCD) coatings using the hot-filament chemical vapor deposition (HF-CVD) process. The performance of the diamond-coated tools has been evaluated by comparing their performance in dry slot m...

Nanocrystals are promising structures, but they are too large for achieving maximum energy storage performance. We show that rescaling 3-nm particles through lithiation followed by delithiation leads to high-performance energy storage by realizing high capacitance close to the theoretical capacitance available via ion-to-atom redox reactions. Reactive force-field (ReaxFF) molecular dynamics sim...

NiO had been claimed to have the potential for application in transparent conducting oxide, electrochromic device for light control, and nonvolatile memory device. However, the detailed study of excitonic transition and light-emission property of NiO has rarely been explored to date. In this work, we demonstrate strong exciton-complex emission of high-quality NiO nanotowers grown by hot-filamen...