In this study, we prepared Fe-Mg-type hydrotalcites (Fe-HT3.0 and Fe-HT5.0) with different molar ratios and evaluated their adsorption capability for nitrite and nitrate ions from aqueous solution. Fe-HT is a typical hydrotalcite-like layered double hydroxide. Adsorption isotherms, as well as the effects of contact time and pH were investigated, and it was found that Fe-HT can adsorb larger amo...

The decomposition mechanism of ammonium nitrate in the gas phase was investigated and fully characterized by means of CBS-QB3 calculations. Five reaction channels were identified, leading to the formation of products (N2, H2O, O2, OH, HNO, NO3) found in the experimental works. The identified mechanism well underlines the origin of the chemical hazard of ammonium nitrate which is related to the ...

[1] This paper reports the first depth profile measurements of methyl, ethyl, isopropyl and n-propyl nitrates in the tropical Pacific Ocean. Depth profile measurements were made at 22 stations during the Project Halocarbon Air Sea Exchange cruise, in warm pool, equatorial, subequatorial, and gyre waters. The highest concentrations, up to several hundred pM of methyl nitrate, were observed in th...

Background. Beetroot consumption has been proposed to improve exercise performance, since the nitrate content of this food is able to stimulate the synthesis of nitric oxide. Objective. The acute effect of 100 g of a beetroot gel containing ~10 mmol of nitrate was tested on the nitric oxide synthesis, on metabolic and biochemical parameters, and on performance in physically active individuals. ...

Determining the isotopic composition of nitrate (NO(3)(-)) in water can prove useful to identify NO(3)(-) sources and to understand its dynamics in aquatic systems. Among the procedures available, the 'ion-exchange resin method' involves extracting NO(3)(-) from freshwater and converting it into solid silver nitrate (AgNO(3)), which is then analysed for (15)N/(14)N and (18)O/(16)O ratios. This ...

The Zn-Cu battery is plagued with both the problems of Cu2+ migration into the anodic chamber as well as the problem of shape change of zinc electrodes, where both of these processes together have historically prevented this type of battery technology from being rechargeable. We herein propose using a monovalent selective cation exchange membrane (CIEM) that through X-ray diffraction experiment...

We recently reported the first multiple oxygen isotope composition of nitrate (NO3 ̄) in ice cores. Post-depositional photolysis and volatilization may alter the isotopic signatures of snowpack nitrate. Therefore, the precise assessment of the geochemical/atmospheric significance of O-isotopic signatures requires information on the relative rates of photolysis (λ > 300 nm) of NO3, NO2O ̄ and NO2O...

Sealed membrane vesicles were isolated from homogenates of sugarbeet (Beta vulgaris L.) taproot by a combination of differential centrifugation, extraction with KI, and dextran gradient centrifugation. Relative to the KI-extracted microsomes, the content of plasma membranes, mitochondrial membranes, and Golgi membranes was much reduced in the final vesicle fraction. A component of ATPase activi...

Forest harvesting disrupts the nitrogen cycle, which may affect stream water quality by increasing nitrate concentrations, reducing pH and acid neutralizing capacity, and mobilizing aluminum and base cations. We tested the application of wood chips derived from logging slash to increase immobilization of N after harvesting, which should reduce nitrate flux to streams. In August 2004, a stand of...

Wet tropical forests growing on highly weathered soil, depleted in rockderived nutrients, yet rich in nitrogen (N), may respond quite differently to anthropogenic N inputs than those growing on younger soils low in N. We evaluated the effects of firsttime and long-term N additions on the pattern and regulation of hydrologic N losses from wet tropical forests located at the extreme ends of a soi...