Here we report a new, bench-top synthesis for iron/iron oxide core/shell nanoparticles via the thermal decomposition of Fe(η(5)-C(6)H(3)Me(4))(2). The iron/iron oxide core/shell nanoparticles are superparamagnetic at room temperature and show improved negative contrast in T(2)-weighted MR imaging compared to pure iron oxides nanoparticles, and have a transverse relaxivity (r(2)) of 332 mM(-1) s...

Presently, the ferrites industry consumes large amounts of iron osides obtained by spray roasting of steel pickling liquors. The aim of this paper is to propose the synthesis of optimal iron osidcs by oxyprecipitation of steel pickling liquors in order to obtain Bahexafenite wit11 high magnetic properties using the ceramic process. As a raw material. i t was used sulphuric liqoors with iron con...

Conventional gravity separation process of iron mineral fines is not very effective. In present work Multi Gravity Separation (MGS) process has been studied. This study was performed on a low-grade iron ore namely goethiticlateritic ore (GLO) from Eastern India. Detailed mineralogical, physical and chemical characteristics of a goethiticlateritic iron ore showed that the sample contained porous...

--This study is an attempt to stabilize the heavy metals present in the municipal solid waste. A hydrothermal processing system was setup with a mixture of ferric sulphate. Experimental results showed the reduction in the heavy metals concentration in the municipal solid waste ash after the treatment with iron oxides. Initial values of Cg, Cu, Pb, Cr, Hg was 0.001 mg/L , 4.322 mg/L , 0.578 mg/L...

Effect of addition of municipal solid waste compost (MSWC) on chromium (Cr) content of submerged rice paddies was studied. Experiments were conducted during the three consecutive wet seasons from 1997 to 1999 on rice grown under submergence, at the Experimental Farm of Calcutta University, India. A sequential extraction method was used to determine the various chromium fractions in MSWC and cow...

An emerging area in chemical science is the study of solid-phase redox reactions using ultrafast time-resolved spectroscopy. We have used molecules of the photoactive dye 2',7'-dichlorofluorescein (DCF) anchored to the surface of iron(III) oxide nanoparticles to create iron(II) surface atoms via photo-initiated interfacial electron transfer. This approach enables time-resolved study of the fate...

Potentiodynamic, impedance measurements were carried out on 304 stainless steel in 0.5N, 1.0, 2.0 and 5.0 N H2SO4 solutions. X-ray photoelectron spectroscopic [XPS] studies carried out on 304 stainless steel in H2SO4 solutions revealed the existence of CrOOH, Cr2O3, -Fe2O3, FeOOH, Mn2O3, Mn3O4, MnS, Ni (OH)2, Ni2O3, NiO, sulphides. The passive film found to contain chromium oxide inner layer an...

Using laboratory methods, we investigate the effect of the presence and mineralogic form of iron on measured proton nuclear magnetic resonance NMR relaxation rates. Five samples of quartz sand were coated with ferrihydrite, goethite, hematite, lepidocrocite, and magnetite. The relaxation rates for these iron-oxide-coated sands saturated with water were measured and compared to the relaxation ra...

Carbothermal reduction is among the oldest chemical processes, commonly used in the production of metals from the corresponding metal oxides or ores (e.g., iron from iron oxides). By using carbon as a reducing agent, decomposition of metal oxides at temperatures much lower than their typical decomposition temperatures can occur. However, a detailed fundamental understanding of such a reaction p...

background diatomite coated by nanoparticles of copper and zinc mixed oxides were used to investigate catalytic oxidation of carbon monoxide. objectives aim of this paper was to investigatediatomite performance as a supporting host to confine the cuo and zno nanoparticles and its catalytic activity for carbon monoxide oxidation. materials and methods the prepared catalysts were characterized by...