Shohreh Fatemi
School of Chemical Engineering, College of Engineering, University of Tehran
[ 1 ] - Application of Zeotype SAPO-34 Molecular Sieve as a Selective Adsorbent for Separation of Ethylene from Ethane
The process of ethylene production from ethane dehydrogenation is one of the interesting processes in the field of conversion the petroleum light gases to the valuable products. In this process, the outlet gaseous product is a combination of ethylene, ethane and hydrogen. Effective separation techniques are required for separation of ethylene from unreacted ethane. Here a new adsorbent approach...
[ 2 ] - Experimental Study and Adsorption Modeling of COD Reduction by Activated Carbon for Wastewater Treatment of Oil Refinery
Application of Granular Activated Carbon (GAC) in adsorption process has been studied for the advanced treatment of municipal and industrial wastewater. Because of entering poisonous compounds such as furfural, phenol and sulfides into the oily wastewater of Tehran refinery, biological aeration basins of wastewater treatment unit may not have the desired performance of COD reductio...
[ 3 ] - Effect of Synthesis Parameters on Phase Purity, Crystallinity and Particle Size of SAPO-34
An account is presented on investigation of the effects of synthesis parameters, i.e., reaction sources, silica to alumina ratio, acid molar ratio and crystallization conditions on the crystallinity, morphology and particle size of SAPO-34. The synthesis conditions were designed to produce small particles with narrow size range. The prepared samples were characterized by XRD and SE...
[ 4 ] - Comparative Study of Carbon Dioxide and Methane Adsorption by Synthesized Fine Particles of SAPO-34 Molecular Sieve
Fine particles Silicoaluminophosphate-34 were synthesized by hydrothermal sol-gel method. The effect of crystallization time, as one of the important synthesis factors on particle size and crystallinity, kinetic and equilibrium adsorption, and selectivity of CO2 / CH4 has been studied in this work. The adsorption isotherms are obtained at mod...
[ 5 ] - Mathematical Modeling of Single and Multi-Component Adsorption Fixed Beds to Rigorously Predict the Mass Transfer Zone and Breakthrough Curves
The aim of the present work is to prepare an adsorption package to simulate adsorption / desorption operation for both single and multi-component systems in an isothermal condition by different mechanisms such as; local adsorption theory and mass transfer resistance (rigorous and approximated methods). Different mass transfer resistance mechanisms of pore, solid and bidispersed diffusion, t...
[ 6 ] - Mathematical Modeling of an Industrial Naphtha Reformer with Three Adiabatic Reactors in Series
A mathematical model for commercial naphtha catalytic reformer of Tehran refinery was developed. This model includes three sequencing fixed beds of Pt/Al2O3 catalyst at the steady state condition using detailed kinetic scheme involving 26 pseudo-components connected by a network of 47 reactions, in the range of C6 to C9 hydrocarbons. The reaction network consisted dehy...
[ 7 ] - Study of Methane Storage and Adsorption Equilibria in Multi-Walled Carbon Nanotubes
Adsorbed natural gas has various advantages and is relatively more economical than liquefaction and compression. Carbon nanotubes can be introduced as a new candidate for natural gas storage. In this study, adsorption of methane was firstly studied on the as-prepared multi-walled carbon nanotubes, and then chemical and physical treatment of MWCNTs was performed to enhance the methane adsorp...
[ 8 ] - The Effect of Coking on Kinetics of HDS Reaction under Steady and Transient States
A study was made of the coking of a commercial fresh sulfide Ni-Mo/Al2O3 catalyst in a fixed-bed reactor. The catalyst was coked using different coke precursors in the gas oil under accelerated conditions at temperatures of 400 to 450°C to yield different deactivated catalysts containing 2-20 wt% C. Two cases were studied; crushed catalyst without diffusional ...
[ 9 ] - Evaluating the Effect of Graphite Source and Operating Conditions on the Synthesis of Graphene Oxide
In this research graphene oxide was synthesized by two methods. These methods were achieved by changing the improved Hummers’ and modified Hummers’ methods. Structure of graphene oxide was characterized by scanning electron microscopy (SEM) images, X-ray diffraction (XRD) patterns, Raman spectroscopy and Fourier transform infrared (FTIR) spectra. According to SEM image, the thickness of graphen...
[ 10 ] - Biodegradation Modeling of Nitrophenolic Pollutant in a Slurry Bubble Reactor
Biodegradation kinetics of 4-nitrophenol (PNP) in aqueous solution by a gram negative soil bacterium, Ralstoniaeutropha was firstly studied in a small scale batch reactor. The degradation of PNP was evaluated at initial PNP concentrations ranging from 3 mg/L to 14 mg/L. The rate of PNP consumption by the bacterium culture was modeled using Monod and Contois kinetics in batch condition. PNP degr...
[ 11 ] - An Experimental Design Study for CH4, C2H6 and C2H4 Adsorption and C2s/CH4 Selectivity on 10X Zeolite
CH4, C2H6 and C2H4 are the most important outlet gaseous of oxidative couple methane (OCM) reaction and this process is a new technology for conversion of natural gas to ethane and ethylene products. In this study, adsorption of OCM outlet hydrocarbons over 10X zeolite has been examined at equilibrium conditions. Temperature and pressure are the most effective operational parameters in the batc...
[ 13 ] - Mathematical Modeling of Adsorption Process of Ethyl Acetate Impurity of Supercritical CO2 on Activated Carbon
A mathematical model is described and applied for adsorption process of ethyl acetate from supercritical CO2 stream on activated carbon particles. This model has the ability of illustrating variation of effluent concentration towards different parameters such as flow rate, temperature and pressure. In this research, a vast area of operational conditions is experienced. Mass transfer resistance ...
[ 14 ] - Ion Exchange Column Performance Model for Separation of Zr(IV) and Hf(IV) in Elution Process
A mathematical model of sorption of Zirconium and Hafnium cations mixture and elution of these ions from a cation exchange resin bed is developed. Sulfuric acid is selected as the eluent for selective separation of Zr and Hf in a packed bed of Dowex cation exchange resin. The column model is a dispersed plug flow model,and assumed to consist of randomly packed synthetic and spherical resin ...
[ 15 ] - Synthesis and application of Ti-incorporated mesoporous silicate in deep oxidesulfurization of DBT from liquid fuel
In-situ synthesis of Ti-incorporated MCM-41 nano catalyst was carried out by the hydrothermal method to prepare a mesoporous catalyst for the oxidative desulfurization reaction (ODS). Oxidative reaction of dibenzothiophene (DBT) as a heavy sulfur compound was evaluated in a solution of n-decane as a model of liquid fuel. The synthesized catalysts were characterized by XRD, FESEM, EDX, TEM, FTIR...
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