Stabilization and inhibition of hepatic microsomal glucose-6-P phosphohydrolase (EC 3.1.3.9) by F- requires the presence of Al3+ ions. At millimolar concentrations, reagent grade NaF inhibited glucose-6-P hydrolysis and protected the enzyme against inactivation induced by heat in the presence of 0.025% (w/v) Triton X-100 or by reaction of the catalytic site with the histidine-specific reagent, ...

The mechanistic basis for cation amelioration of Al rhizotoxicity in soybean was investigated through a series of studies comparing protective effects of Ca and Mg against Al inhibition of root elongation in a background 0.8 mM CaSO4 solution (pH 4.3). A modified Gouy-Chapman-Stern model was used to evaluate the effect of cations on electrical potential and Al3+ activity at root plasma membrane...

Cast, coarse-grained Al-Sc alloys are interesting candidates for high temperature, creepresistant applications due to the formation of a high number density of nanometer sized Al3Sc precipitates [1]. Upon addition of Yb to Al-Sc alloys, Yb replaces the Sc forming Al3(Sc1-xYbx) precipitates (L12 structure) [2]. The resulting alloys have higher creep resistance due to the larger lattice parameter...

When Fe2+ ions are added to rat-liver microsomes, lipid peroxidation begins after a short lag period. Fe2+-dependent peroxidation in the first few minutes of the incubation can be increased by adding Fe3+, ascorbic acid or Pb2+ ions; these stimulations are not additive. By contrast, Pb2+ ions inhibit peroxidation of microsomes in the presence of Fe3+/ascorbate or Fe3+-ADP/NADPH. In liposomes ma...

The morphology of nucleus and nucleolus is powerful indicator of physiological and pathological conditions. The specific staining of nucleolus recently gained much attention due to the limited and expensive availability of the only existing stain "SYTO RNA-Select". Here, a new multifunctional salen type ligand (L1) and its Al3+ complex (1) are designed and synthesized. L1 acts as a chemosensor ...

The combination of new containerless sample and high intensity synchrotron source technologies has enabled the X-ray diffraction pattern from a molten oxide (Al2O3) to be determined for the first time (Ansell et al. Phys. ReV. Lett. 1997, 78, 464).1 Here we show that the liquid-state diffraction pattern, predicted from a computer simulation with a potential derived from the ground-state crystal...

Highly b-oriented zeolite ZSM-5 films are critical for applications in catalysis and separations and may serve as models to study diffusion and catalytic properties in single zeolite channels. However, the introduction of catalytically active Al3+ usually disrupts the orientation of zeolite films. Herein, using structure-directing agents with hydroxy groups, we demonstrate a new method to prepa...

The influence of some inorganic (K+, Mg2+, and Al3+) and organic CnH(2n+1)SO3-, n = 12 and 14) ions was studied on the hemolysis of erythrocytes (RBC) caused by organolead compounds (tripropyllead--TPL, tributyllead--TBL and triphenyllead--TPhL chlorides). It was found that sulfonate anions increased the hemolytic effect induced by triorganoleads, while inorganic cations protected RBC against t...