The new area of lithio(thiocyanato)cuprates has been developed. Using inexpensive, stable and safe CuSCN for their preparation, these complexes revealed Lipshutz-type dimeric motifs with solvent-dependent point group identities; planar, boat-shaped and chair shaped conformers are seen in the solid state. In solution, both Lipshutz-type and Gilman structures are clearly seen. Since the advent in...

Infrared (IR) properties of k-(ET-C4)2Cu(CN)[N(CN)2] crystals in the normal (metallic) phase are reported. Deviations from conventional metallic properties are found and assigned to a strong electron correlation effect. # 2002 Elsevier Science B.V. All rights reserved.

Title Femtosecond Carrier Relaxation Dynamics and Photoinduced Phase Separation in κ-(BEDT-TTF)2Cu[N(CN)2]X (X = Br, Cl) Author(s) Toda, Y.; Mertelj, T.; Naito, T.; Mihailovic, D. Citation Physical Review Letters, 107(22): 227002 Issue Date 2011-11-25 DOI Doc URL http://hdl.handle.net/2115/47741 Right © 2011 American Physical Society Type article Additional Information File Information PRL107-2...

The pressure dependence of the inverse square of the magnetic penetration depth λ in κ-(ET)2Cu(NCS)2 was measured by Larkin, et al. According to the paper, λ −2 behaves differently under low pressure and under high pressure. Under low pressure, the development of λ just below T = Tc is rapid compared to the case under high pressure. Moreover, Tc in κ-(ET)2Cu(NCS)2 increases under c-axis pressur...

In order to investigate the coordination chemistry of O-alkyl N-aryl thiocarbamate ligands toward coinage metals, CuBr was reacted with one equivalent MeOC(=S)N(H)Ph L in MeCN solution afford 1D-polymeric title compound [{Cu(μ2-Br)2Cu}{μ2-MeOC(=S)N(H)Ph}2]n CP1. Compound 1 characterized by IR spectroscopy and an elemental analysis. The formation a polymeric 1D ribbon built upon μ2-bridging brom...