نتایج جستجو برای: 12 aryl 8
تعداد نتایج: 1115919 فیلتر نتایج به سال:
واکنش های تک ظرفی دو مینو، آریل آمین ها، آلکیل پروپیولات ها، ایزاتین و ایندول در حلال اتانول و در دمای اتاق با استفاده از fecl3 به عنوان کاتالیزور مورد بررسی قرار گرفت، که منجر به تشکیل محصول 2-(2-oxo-1,2-dihydro-1h-[3,3]biindolyl-3-yl)-3-aryl amine-acrylic acid alkyl ester با راندمان بالا گردید.
Nonracemic ethano-bridged Tröger bases are prepared using CuTC-catalyzed decompositions of diazo compounds. Excellent levels of diastereo- and enantio-control (dr and ee up to 12:1 and 95% respectively) are now obtained with aryl diazoketone precursors.
Based on the well-defined five-membered aryl gold(iii) complexes, [Au(tpy)X2] (3a and 3b) and [AuBr(Ph)(tpy)] (7), as well as the aryl gold(iii) complex [AuCl2(Ph)(tpy)] (8) (tpy = 2-(o-tolyl)pyridine) as reliable models, we present a detailed study of the mechanism for gold(iii)-catalyzed oxidative cross-coupling reactions between cycloaurable arenes and arylboronic acids. Here we report the d...
The two acid hydrolases ‘acid phosphatase’ (orthophosphoric monoester phosphohydrolase, EC 3.1.3.2) and ‘aryl sulphatase’ (aryl-sulphate sulphohydrolase, EC 3.1.6.1) are both enzymes which are known to be present in the lysosomes of almost all cell types [cf. l] . Histochemical studies have revealed apparent activity of acid phosphatase in both hepatic parenchymal and Kupffer cells [2,3] , and ...
In the structure of the title compound, C(12)H(14)N(2)O(3), the piperidine ring adopts a chair conformation and the aryl substitutent occupies an equatorial position.
Aryl hydrazine and hydrazide analogues were synthesized based on p-tolyl hydrazine, isolated as a breakdown product of a secondary metabolite from the mushroom, Agaricus bisporus, and tested to be highly active molecule than 5-fluorouracil in in vitro anticancer studies. The synthesized analogues were tested for anticancer activity using NCI protocol. Anolgues 12 and 15 emerged as molecules wit...
5-Amino-N-aryl-3-[(4-methoxyphenyl)amino]-1H-pyrazole-4-carboxamides 4a-c were synthesized by the reaction of N-(aryl)-2-cyano-3-[(4-methoxyphenyl)amino]-3-(methylthio)acrylamides 3a-c with hydrazine hydrate in ethanol. The reaction of 5-amino-N-aryl-1H-pyrazoles 4a-c with acetylacetone 5 or 2-(4-methoxybenzylidene)malononitrile 8 yielded the pyrazolo[1,5-a]pyrimidine derivatives 7a-c and 10a-c...
Abstract The core‐shell magnetic mesoporous microspheres immobilized NHC‐palladacycles (NHC= N ‐heterocyclic carbene) catalyst with constrained aliphatic linker group (Fe 3 O 4 @mSiO 2 @NHC−Pd) were readily prepared by the well‐designed method, which showed higher palladium loading (0.20 mmol g −1 ) and catalytic activity than non‐mesoporous catalysts @SiO same process in Suzuki‐Miyaura cross‐c...
synthesis of 4-(n,n- dimethylamino)-3-aryl-3-butene-2-one, ethyl-5-aryl-4-oxo-4h-pyran-2-carboxylate, ethyl-5-aryl-4-pyridones-2-carboxylate and 5-aryl-3-cyano-5-methyl-2-pyridones (aryl=3-thienyl, 2-furyl) are described.
Lithium and nickel complexes bearing quinoline-based ligands have been synthesized and characterized. Reaction of 8-azidoquinoline with Ph(2)PNHR (R = p-MeC(6)H(4), Bu(t)) affords N-(8-quinolyl)iminophosphoranes RNHP(Ph(2))=N(8-C(9)H(6)N) (1a, R = p-MeC(6)H(4); 1b, R = Bu(t). C(9)H(6)N = quinolyl)). Reaction of 1a with (DME)NiCl(2) generates a nickel complex [NiCl(2){N(8-C(9)H(6)N)=P(Ph(2))NH(p...
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