Experimental For the synthesis of: Sodium 2'-(Dicyclohexylphosphanyl)-2,6-diisopropyl-(1,1-biphenyl)-4-sulfonate (sXPhos) 12 4 Standard Reaction Procedure of 5-bromoindole 15 under reflux: 5 Microwave Reaction Procedure of 5-bromoindole 15: 5 Standard Microwave Reaction Procedure for Tryptophans: 5 (S)-2-Amino-3-(5-(phenylethynyl)-1H-indol-3-yl)propanoic acid 19 6 (S)-2-Amino-3-5-((3-fluorophen...

We used molecular dynamics (MD) techniques to examine the encapsulation of Bengal Rose (BR) molecules in the Meijer dendrimer box (DBox) formed by the addition of tert-butyloxycarbonyl-L-Phe (tBOC-L-Phe) cap molecules to the 64 terminal primary amines of a fifth generation poly(propyleneimine) (PPI-5) dendrimer. Using a large periodic box (including DBox, four to six BR, and CH2Cl2 solvent, tot...

The title compound, [Fe(C(5)H(5))(C(8)H(13)N)]Br, is isotypic with the analogous chloride compound. The Fe-C bond lengths are in the range 2.020 (6)-2.048 (7) Å. In the crystal, the cations and bromide anions are connected by N(+)-H⋯Br(-) hydrogen bonds.

The title compound, [WMoBr(C(5)H(5))(CO)(3)], is built up from a pseudo-square-pyramidal piano-stool coordination around the Mo atom, the important geometry being Mo-W = 2.6872 (7) Å, W-Br = 2.5591 (9) Å and Mo-W-Br = 158.35 (3)°.

The six-membered ring in the title salt, C(5)H(12)NO(+)·Br(-), has a chair conformation. In the crystal, the cations are linked to the anions by N-H⋯Br hydrogen bonds.

Brassinosteroids (BR) play important roles in plant growth and development. Although BR receptors have been intensively studied in Arabidopsis, the BR receptors in soybean remain largely unknown. Here, in addition to the known receptor gene Glyma06g15270 (GmBRI1a), we identified five putative BR receptor genes in the soybean genome: GmBRI1b, GmBRL1a, GmBRL1b, GmBRL2a, and GmBRL2b. Analysis of t...

The mol-ecule of the title compound, C(11)H(8)BrN(3)O, is close to planar (r.m.s. deviation of all 16 non-H atoms = 0.103 Å), a conformation stabilized by an intra-molecular N-H⋯N hydrogen bond, which generates an S(5) ring. In the crystal structure, supra-molecular chains mediated by C-H⋯O contacts (along a) are linked into a double layer via N⋯Br halogen bonds [3.207 (5) Å] and C-Br⋯π inter-a...

The title complex, [RuBr(2)(C(5)H(5)N)(4)], contains two independent complex mol-ecules in each of which the Ru(II) atom is located on a site of 222 symmetry and has a distorted octa-hedral coordination geometry with four pyridine N atoms and two Br atoms. The Br aroms are trans-disposed as a result of symmetry.

In the title compound, [CuBr(C(10)H(8)N(2))(2)]Br·BrCH(2)COOH·0.5H(2)O, the Cu(II) ion is coordinated by four N atoms [Cu-N = 1.985 (6)-2.125 (7) Å] from two 2,2'-bipyridine ligand mol-ecules and a bromide anion [Cu-Br = 2.471 (2) Å] in a distorted trigonal-bipyramidal geometry. Short centroid-centroid distances [3.762 (5) and 3.867 (5) Å] between the aromatic rings of neighbouring cations sugg...

In the title compound, C17H21BrO2S, the cyclo-hexyl ring adopts a chair conformation and the aryl-sulfinyl unit is positioned equatorially relative to the cyclo-hexyl group. The benzo-furan unit is essentially planar, with an r.m.s. deviation of 0.016 (2) Å. In the crystal, mol-ecules are linked by weak C-H⋯O, C-H⋯π and Br⋯π [3.663 (2) Å] inter-actions, resulting in a three-dimensional network....