Metal-amine solutions provide a unique arena in which to study electrons in solution, and to tune the electron density from the extremes of electrolytic through to true metallic behavior. The existence and structure of a new class of concentrated metal-amine liquid, Li-NH3 -MeNH2 , is presented in which the mixed solvent produces a novel type of electron solvation and delocalization that is fun...

Block, permeation, and agonist action of small organic amine compounds were studied in acetylcholine receptor (AChR) channels. Single channel conductances were calculated from fluctuation analysis at the frog neuromuscular junction and measured by patch clamp of cultured rat myotubes. The conductance was depressed by a few millimolar external dimethylammonium, arginine, dimethyldiethanolammoniu...

Binary and ternary complexes of copper(II) with l-glutamic acid (Glu) and diamines 1,3-diaminopropane and 1,4-diaminobutane, putrescine (tn, Put), as well as adducts formed in the metal-free systems, have been investigated in aqueous solutions. The types of complexes formed and their overall stability constants were established on the basis of computer analysis of potentiometric results. The re...

Accurate modeling of thermodynamic properties for CO2 absorption in aqueous alkanolamine solutions is essential for the simulation and design of such CO2 capture processes. In this study, we use the Electrolyte Nonrandom Two-Liquid activity coefficient model to develop a rigorous and thermodynamically consistent representation for the MDEA-H2O-CO2 system. The vapor-liquid equilibrium (VLE), hea...

A bubble column was used to study the heat effect on CO2 absorption in methydiethanolamine solutions and on volumetric mass transfer coefficient. It was found that the temperature varied until 4 oC between the beginning and the end of the process. Our studies provide an empirical correlation type Boltzmann to estimate the temperature at different amine concentration (0-1M) and gas flow rate (10...

Complexation with cyclam increases the rate of reduction of perchlorate ion by TiIII (in acidic, aqueous, 4 mol dm–3 LiCl solutions at 25 °C) relative to the rate of the corresponding reduction of Ti3+. A modified cyclam with pendant amine and p-aminobenzyl functional groups is more effective in this regard than is cyclam itself. Both redox reactions are acid catalyzed. The data is consistent w...

This study used monoethanolamine (MEA) as an amine-based solvent, which was blended with secondary amines (DIPA), tertiary amines, stereo and piperazine (PZ) to prepare mixed at the required concentrations, were test solvents. To search for best-mixed a continuous bubble-column scrubber adopted explore performance of solvents presented in this study. The solvent regeneration also carried out di...

In this investigation, nucleate boiling heat transfer coefficients were experimentally measured during pool boiling of mixtures, consisting of water/monoethanolamine and water/diethanolamine on a horizontal heating rod, under atmospheric pressure. The experiment was carried out below 205 kW.m-2 heat flux, over a wide range of concentrations. These experiments include, measurement of pool boilin...