Nonaqueous liquid electrolyte system based dimethyl sulfoxide DMSO and magnesium bromide (MgBr2) is synthesized via 'Solvent-in-Salt' method for the application in magnesium battery. Optimized composition of MgBr2/DMSO electrolyte exhibits high ionic conductivity of 10(-2) S/cm at ambient temperature. This study discusses different concentrations from 0 to 5.4 M of magnesium salt, representing ...

Based on a coherent state representation of noise operator and an ensemble averaging procedure using Wigner canonical thermal distribution for harmonic oscillators, a generalized quantum Langevin equation has been recently developed [Phys. Rev. E 65, 021109 (2002); 66, 051106 (2002)] to derive the equations of motion for probability distribution functions in c-number phase-space. We extend the ...

We describe a general method of finding the transport properties of molecules in polymer films by photolysis. Poly(methyl methacrylate) samples held at different temperatures are exposed to UV radiation at discrete wavelengths, and the time evolution of the volatile photoproducts are detected with a quadrupole mass spectrometer. A diffusion model is used to fit the experimental data and deduce ...

The concept of 'fragility' constitutes a central point of the glass transition science serving as the 'universal' metric linking previtreous dynamics of qualitatively distinct systems. Finding the fundamental meaning of fragility is the 'condicio sine qua' for reaching the long expected conceptual breakthrough in this domain. This report shows that fragility is determined by the ratio between t...

The preparation of a new family of mixed transition metal/lanthanide clusters is reported. The reaction of [Mn3O(O2CPh)6(py)2(H2O)] with Ln(NO3)3 (Ln = Nd, Gd, Dy, Ho, and Eu) in a 1:2 molar ratio in MeOH/MeCN (1:20 v/v) leads to dark crystals in 55-60% isolated yield of complexes all containing the [Mn11Ln4]45+ core. The Dy compound has been found to give out-of-phase AC susceptibility signals...

Gel polymer electrolytes (GPEs) are developed using poly(1-vinylpyrrolidone-co-vinyl acetate) [P(VP-co-VAc)] as the host polymer, lithium bis(trifluoromethane) sulfonimide [LiTFSI] as the lithium salt and ionic liquid, and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl) imide [EMImTFSI] by using solution casting technique. The effect of ionic liquid on ionic conductivity is studied and...

Reliable analysis of any experimental data is always difficult due to the presence of noise and other types of errors. This paper analyzes data obtained from photoluminescence measurement, after annealing of interdiffused Quantum Well hetrostructures, using an Adaptive Real coded Quantum inspired Evolutionary Algorithm (ARQiEA). The proposed algorithm directly computes interdiffusion parameters...

Oncopeltus fasciatus, Chemical Defence, Cardenolide Sequestration, Carrier-Mediated Uptake, Cardenolide Carrier Oncopeltus fasciatus (Hemiptera) is morphologically and physiologically adapted to seques­ ter cardiac glycosides for its chemical defence against predators. As a prerequisite for carde­ nolide utilization this bug has to take up and store the dietary cardenolides. Using isolated midg...

We report photoluminescence (PL) and reflectivity measurements of Zn0.5Cd0.5Se epilayers grown by molecular beam epitaxy on InP substrates. The low-temperature PL spectra are dominated by asymmetric lines, which can be deconvoluted into two Gaussian peaks with a separation of ,8 meV. The behavior of these peaks is studied as a function of excitation intensity and temperature, revealing that the...

A quantitative measurement method with FT-IR was proposed for a thermal degradation analysis of nitrile-butadiene rubber (NBR). An NBR film was prepared as a model sample on a barium fluoride (BaF2) crystal plate, which was subjected to a heat treatment. The absorbances of various functional groups were measured directly by FT-IR after thermal degradation at high temperatures. By measuring the ...