Hydroxyacetone (HA) is mainly produced in the atmosphere from oxidation of hydrocarbons of the type, CH3(R)C=CH2. Tuazon and Atkinson (1990) reported HA yield of 41% from the OH-initiated oxidation of methacrolein in the presence of NOx. Since methacrolein is a major product of isoprene oxidation (Carter and Atkinson, 1996), isoprene, a key biogenic hydrocarbon, is therefore expected to be an i...