نتایج جستجو برای: based catalyst
تعداد نتایج: 2970333 فیلتر نتایج به سال:
Nickel(0)-catalyzed cross-coupling of heteroaryl-containing diarylmethanes with both aryl bromides and chlorides has been achieved. The success of this reaction relies on the introduction of a unique nickel/NIXANTPHOS-based catalyst system, which provides a direct route to triarylmethanes from heteroaryl-containing diarylmethanes. Reactivity studies indicate the Ni(NIXANTPHOS)-based catalyst ex...
The adsorption properties of CO and H2 on iron-based catalyst with addition of Zr and Ni were investigated using temperature programmed desorption process. It was found that on the carburized iron-based catalysts, molecular state and dissociative state CO existed together. The addition of Zr was preferential for the molecular state adsorption of CO on iron-based catalyst and the presence of Ni ...
Density functional theory (DFT) has been applied to study potential ammonia borane (AB) dehydrogenation pathways via new bifunctional ruthenium-based catalysts, alongside their computationally-designed iron-based counterparts (i.e., four catalysts), using the wB97XD (dispersion-included) functional. The efficiency of each catalyst was under scrutiny based on the addition of ammonia borane, with...
An Ethanol SCR for NOx Purification: Performance Evaluation on Engine Bench and Demonstration on Bus
NOx –SCR over Ag/ Al2O3 catalyst using ethanol (C2H5OH) as a reductant has proven its ability to significantly reduce NOx emission in a simulated engine exhaust gas environment. However the real engine exhaust gas environment is too complicated to be simulated. Therefore,the performance evaluation of the Ag/ Al2O3 catalyst in real exhaust gas environment is necessary. Moreover, the ethanol dosi...
The aim of this paper is to analyze how different catalyst activity profiles influence the operating strategies of industrial reactors. Based on this analysis a method that can be used to transform information given by laboratory reactor experiments into a form which can be used to estimate the productivity of the catalyst and the quality properties of polymers under industrial conditions is pr...
We demonstrate that non-stoichiometric lithium imide is a highly active catalyst for the production of highpurity hydrogen from ammonia, with superior ammonia decomposition activity to a number of other catalyst materials. Neutron powder diffraction measurements reveal that the catalyst deviates from pure imide stoichiometry under ammonia flow, with active catalytic behaviour observed across a ...
Almost three quarters of the hydrocarbon (HC) emissions emitted by an automobile in a typical drive-cycle are produced during the first three minutes of its operation called the coldstart period. In this paper, we propose a way to decrease cold start emissions. A Model-Based paradigm is used to aid the generation of an efficient controller. The controller is built around a mean value engine mod...
A solid Ca/Al composite oxide-based alkaline catalyst containing Ca(12)Al(14)O(33) and CaO was prepared by chemical synthesis and thermal activation from sodium aluminate solution and calcium hydroxide emulsion. The effect of calcination temperatures ranging from 120 °C to 1000 °C on activity of the catalyst was investigated. The catalyst calcined at 600 °C showed the highest activity with >94%...
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