نتایج جستجو برای: bioconjugation

تعداد نتایج: 645  

2016
Peng Dai Chi Zhang Matthew Welborn James J. Shepherd Tianyu Zhu Troy Van Voorhis Bradley L. Pentelute

Highly efficient and selective chemical reactions are desired. For small molecule chemistry, the reaction rate can be varied by changing the concentration, temperature, and solvent used. In contrast for large biomolecules, the reaction rate is difficult to modify by adjusting these variables because stringent biocompatible reaction conditions are required. Here we show that adding salts can cha...

Journal: :Organic letters 2012
Zhao Yuan Gui-Chao Kuang Ronald J Clark Lei Zhu

Unsymmetrical bisazides containing chelating and nonchelating azido groups undergo chemoselective three-component copper(I)-catalyzed azide-alkyne conjugation reactions with two different alkyne molecules. In conjunction with the reactivity gap between aromatic and aliphatic alkynes, a bistriazole molecule can be generated with excellent regioselectivity by mixing two alkynes and a bisazide in ...

Journal: :Chemical communications 2016
Johnathan C Maza Zachary M Nimmo Douglas D Young

The importance of bioconjugates within the field of chemistry drives the need for novel methodologies for their preparation. Well-defined and stable bioconjugates are easily accessible via the utilization of unnatural amino acids (UAAs). As such, we have synthesized and incorporated two new UAAs into green fluorescent protein, and optimized a novel Cadiot-Chodkiewicz bioconjugation, effectively...

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