We have developed a general predictive method for vapor pressures and enthalpies of vaporization based on the calculation of the solvation free energy that consists of three components; the electrostatic, dispersion, and cavity formation contributions. The electrostatic contribution is determined using the quantum mechanical COSMO solvation model. Thermodynamic perturbation theory for hard-core...

1,3-Butadiene, BD is produced from C4-cut by extractive distillation. The separation of 1,3-Butadiene from C4-cut is not possible through the conventional distillation processes, because several mixtures have consisted of close boiling points constituents and make azeotrope. The BASF extraction distillation process in BD unit of Jam and Amirkabir Petrochemical Company improves the relative vola...

OBJECTIVES To evaluate the effect of domestic boiling practice on the contents of water soluble vitamins of loose milk and quantitative comparison of these vitamins in Ultra High Temperature (UHT) treated packaged milk with that of boiled loose milk. METHODS Loose milk samples were collected from various localities of Karachi city (Pakistan). These samples were boiled in simulated household c...

The use of immiscible liquids for cooling of surfaces with high heat generation density is proposed based on the experimental verification of its superior cooling characteristics in fundamental systems of pool boiling and flow boiling in a tube. For the purpose of practical applications, however, heat transfer characteristics due to flow boiling in narrow rectangular channels with different sma...

Constant temperature and pressure molecular-dynamics simulations in conjunction with constant pressure and enthalpy simulations, designed to examine the threshold behavior in laser ablation, demonstrate that the rate of homogeneous nucleation (explosive boiling) increases sharply in a very narrow temperature range at approximately 90% of the critical temperature. Moreover, the homogeneous nucle...

Photographic observations of the boiling phenomena have played an important role in gaining insight into the boiling mechanism. This paper presents a brief historical review of the available literature on the photographic studies in pool and flow boiling. This is followed by the results of the photographic studies conducted in the author’s laboratory on liquid droplets impinging on a heated sur...

Film boiling on a horizontal elliptical tube immersed in external flowing nitrogen liquid is investigated in the present paper. The isothermal wall temperature is high enough to induce turbulent film boiling, and then a continuous vapor film runs upward over the surface. The high velocity of the flowing saturated liquid at the boundary layer is determined by potential flow theory. In addition, ...