CS2 hydrolase, a zinc-dependent enzyme that converts carbon disulfide to carbon dioxide and hydrogen sulfide, exists as a mixture of octameric ring and hexadecameric catenane forms in solution. A combination of size exclusion chromatography, multi-angle laser light scattering, and mass spectrometric analyses revealed that the unusual catenane structure is not an artefact, but a naturally occurr...

The etiology of Parkinsonism may be multifactorial. Exposure to certain toxins (for example manganese dust, carbon disulfide) and severe carbon monoxide poisoning may play a role. It is also seen in people who took MPTP recreationally — which converts to a neurotoxin in the body. Other drugs and medication can cause a reversible form of this disease. Postencephalitic parkinsonism is becoming mo...

Background: Nanotechnology is a new approach that has been lionized in recent years. One of its applications is its consumption as an absorbent. In this study, the single-wall carbon nanotubes (SWCNTs) were used as an absorbent for sampling benzene in the air. Materials and Methods: For this study, SWCNTs manufactured by Iran and SKC’s activated charcoal were used for sampling benzene vapors....

Dibenzothiophene is a sulfur heterocycle found in crude oils and coal. The biodegradation of dibenzothiophene through the Kodama pathway by Pseudomonas sp. strain BT1d leads to the formation of three disulfides: 2-oxo-2-(2-thiophenyl)ethanoic acid disulfide, 2-oxo-2-(2-thiophenyl)ethanoic acid-2-benzoic acid disulfide, and 2,2'-dithiodibenzoic acid. When provided as the carbon and sulfur source...

The electroreduction of water for sustainable hydrogen production is a critical component of several developing clean-energy technologies, such as water splitting and fuel cells. However, finding a cheap and efficient alternative catalyst to replace currently used platinum-based catalysts is still a prerequisite for the commercialization of these technologies. Here we report a robust and highly...

The chiral N-heterocyclic carbene-catalyzed [2+2+2] cycloaddition of ketenes and carbon disulfide was realized to give the cycloadduct of 1,3-oxathian-6-ones in good yields with excellent enantioselectivities.