Many synthetically useful reactions are catalyzed by cofactor-dependent enzymes. As cofactors represent a major cost factor, methods for efficient cofactor regeneration are required especially for large-scale synthetic applications. In order to generate a novel and efficient host chassis for bioreductions, we engineered the methanol utilization pathway of Pichia pastoris for improved NADH regen...

Effective solid acid catalysts play a key role to produce high-quality biodiesel through triglyceride transesterification. The present work describes a facile technique for the synthesis of a high-performing sulfonated multi-walled carbon nanotube (S-MWCNTs) solid acid catalyst for fatty acid ethyl ester (biodiesel) production. The results indicated that S-MWCNTs possessed high acidity due to t...

Deactivation of commercially relevant cobalt catalysts for Low Temperature Fischer-Tropsch (LTFT) synthesis is discussed with a focus on the two main long-term deactivation mechanisms proposed: Carbon deposits covering the catalytic surface and re-oxidation of the cobalt metal. There is a great variety in commercial, demonstration or pilot LTFT operations in terms of reactor systems employed, c...

The performance of a combined catalyst and sorbent material designed for reforming hydrocarbons was evaluated by reacting methane with steam at different temperatures and pressures in a reactor packed with the material. The combined material was in the form of small spherical pellets comprised of a sorbent core of lime encased in a porous shell made largely of sintered alumina that supported a ...

The V2O5-modified palygorskite (V2O5/PG catalysts) were prepared and used for Hg0 removal in simulated flue gas at low temperature. It was found that the V2O5/PG catalyst had excellent performance 150 °C. O2 exhibited a positive effect on over V2O5/PG, while SO2 H2O showed an inhibiting effect. However, efficiency promotion trend presence of H2O, SO2, O2. Brunauer–Emmett–Teller (BET) method, sc...

The liquid phase esterification of phenyl acetic acid with p-cresol over different metal cation exchanged montmorillonite nanoclays yields p-cresyl phenyl acetate. Different metal cation exchanged montmorillonite nanoclays (M n+ = Al3+, Zn2+, Mn2+, Fe3+, Cu2+) were prepared and the catalytic activity was studied. The esterification reaction was conducted by varying molar ratio of the reactants,...

14 15 The catalytic activity and durability of 2 wt. % Pd/Al2O3 in powder and washcoated on cordierite 16 monoliths were examined for the liquid phase hydrodechlorination (LPHDC) of polychlorinated 17 dibenzo-p-dioxins/polychlorinated dibenzofurans (PCDD/Fs). NaOH was employed as a 18 neutralizing agent, and 2-propanol was used as a hydrogen donor and a solvent. Fresh and spent 19 powder and mo...

Catalysis is one of the core technologies in modern chemistry, energy industry and recently with promising application in biorefinery for sustainable fuels and energy production. Reducing the cost of catalyst systems is one of the ways in which technology can be brought closer to full commercialisation. The replacement of noble metals by cheaper non-precious alternatives would bring valuable sa...

Catalysis in pharma manufacturing processes is typically homogeneous, expensive and with hard catalyst recovery/regeneration. Herein an enzyme-inspired dry-powder molecularly imprinted polymeric (MIP) system was designed for fast, selective oxidation of a cholesterol derivative easy regeneration. The strategy involved the synthesis template-monomer (T:M) complex followed by crosslinked polymeri...