a highly efficient procedure for the synthesis of 1,8-dioxo-octahydroxanthenes under mild, green and solvent-free condition by using hosa as a dual role catalyst is described. this is the first report of catalytic activity of hosa.

To improve the photo-catalytic degradation of salicylic acid, we reported the fabrication of ordered TiO2 nanotube arrays by a simple and effective two-step anodization method and then these TiO2 nanotubes treated in a methanol solution under UV light irradiation. The TiO2 nanotubes prepared in the two-step anodization process showed better photo-catalytic activity than TiO2 nanotubes prepared ...

lamno3 and lamno3/zsm-5 nano catalysts were synthesized by pechini method and their physical-chemical properties were characterized using xrd, ftir, sem-edx, uv-vis drs, bet surface area and tpr. the correlation between characteristic properties and activity of catalysts were investigated. the catalytic performance of the catalysts was evaluated in combustion of 2-propanol and compared with 1% ...

TiO2/Magnetit and TiO2/Nd/Magnetit were prepared and used for photocatalytic decomposition of the methylorange as a pollutant. TiO2 and TiO2/Nd were prepared by sol gel method and were characterized using XRD, FT IR and TEM. The prepared catalysts were deposited on magnetite surface to have a catalyst with magnetite core. So the catalyst can be separated easily from the waste solution by a magn...

Polyphenol oxidase from Black mulberrys was extracted and partially purified through (NH4)2SO4 precipitation, dialysis and ion exchange chromatography. P-cresol was the better substrate for cresolase activity with a Km (11.5 mM) and catechol for catecholase activity with Km (6.4 mM) at pH 5. Km for cresolase and catecholase activity of IsoPPOII at pH 6.5 were 12 and 8.5 and for IsoPPOIII at pH ...

in this work, benzyl alcohol was obtained in 96% excellent yield by hydrolysis of benzyl chloride catalyzedby the recyclable temperature-dependant phase-separation system that comprised the ionic liquid peg1000-dail[bf4], toluene and ferric sulfate under homogeneous catalysis in aqueous media. this novel methodnot only enhanced the yield, but also made the operating units easy workup. the catal...

Au is usually viewed as an inert metal, but surprisingly it has been found that Au nanoparticles less than 3–5 nm in diameter are catalytically active for several chemical reactions. We discuss the origin of this effect, focusing on the way in which the chemical activity of Au may change with particle size. We find that the fraction of low-coordinated Au atoms scales approximately with the cata...

Catalytic DNA sequences (deoxyribozymes, DNA enzymes, or DNAzymes) have been identified by in vitro selection for various catalytic activities. Expanding the limits of DNA catalysis is an important fundamental objective and may facilitate practical utility of catalysts that can be obtained from entirely unbiased (random) sequence populations. In this study, we show that DNA can catalyze Zn(2+)-...

palladium nanoparticles supported on multi-walled carbon nanotubes (pd/mwcnts) have been synthesized using a modified polyol reduction method and its performance in methanol oxidation reactions has evaluated. the morphology of palladium on mwcnts was characterized by scanning electron microscopy (sem) and transmission electron microscopy (tem). the catalytic performance of synthesized catalyst ...