Oxygen transport to vertebrate tissues is dependent upon (a) the intrinsic O2-binding properties of haemoglobin (Hb) and (b) modulation by allosteric effectors, such as nucleoside triphosphates (NTP), that depress Hb O2-affinity in fish red cells. While some species, such as flatfish, primarily use adenosine triphosphate (ATP) to modulate O2-binding to Hb, others, such as eel and carp, also use...

This work is a preliminary examination of mechanistic issues on the comparative corrosion performance of regular epoxy-coated rebar (ECR) and dual polymer-zinc coated reinforcement (DCR) in simulated concrete pore solution with and without chloride ions, at polarizations from +100 mV to -1000 mV in the saturated calomel electrode (SCE) scale and exposure periods of 1 month or longer. Both mater...

Chitosan (CS) is a versatile biopolymer whose morphological and chemico-physical properties can be designed for a variety of biomedical applications. Taking advantage of its electrolytic nature, cathodic polarization allows CS deposition on electrically conductive substrates, resulting in thin porous structures with tunable morphology. Here we propose an easy method to obtain CS membranes with ...

This paper deals with the urgent issue of the search of new drugs based on plant raw materials that have an influence on various stages of oxidation processes occurring in the human body. The aim of this paper is to determine the antioxidant activity of the bilberry extracts that are used in the medicine practice by a cathodic voltammetry method. We consider the influence of water and alcohol b...

Cathodic prevention (CPre) technique is a promising method and has been used for the past two decades to prevent steel from corrosion in concrete structures. However, wide application of this technique has been restricted due to high costs of anode materials. In order to lower the cost and further improve this technique, carbon fiber composite anode has been introduced as an alternative anode m...

In conjugated polymer devices that switch from one oxidation level to another, such as artificial muscles, it is important to understand memory effects that stem from conformational relaxation movements of the polymer chains. Chronoamperometry during electrochemical switching of polypyrrole doped with dodecylbenzenesulfonate, PPy(DBS), is used to gain insight into the conformational relaxation ...

Microbial biofilms produce electrochemical interactions with metal surfaces by following a wide variety of different electron exchange pathways. Reviewing the mechanisms identified in the biocorrosion of steels leads us to distinguish direct and indirect mechanisms for biofilm-catalysed cathodic reactions. Indirect mechanisms are due to the production of metal oxides or hydrogen peroxide (aerob...

Title of Thesis: CHRONOAMPEROMETRIC STUDY OF CONFORMATIONAL RELAXATION IN PPY(DBS) Bryan Jason West, Master of Science, 2008 Thesis directed by: Professor Elisabeth Smela Department of Mechanical Engineering Professor Benjamin Shapiro Department of Aerospace Engineering In conjugated polymer devices that switch from one oxidation level to another, such as artificial muscles, it is important to ...

Changes in peroxidase activity as well as isozyme peroxidase pattern were analyzed in five cell wall (CW) fractions of barley roots exposed to 1mM CdCl2 for 48 and 72 h. Whereas strong inhibition of peroxidase activity was detected in fraction CW I and weak inhibition in fractions CW II, III and IV, strong activation of peroxidase was observed in fraction V after Cd application. Despite the inh...

The redox behavior of spironolactone (SP) drug in Britton-Robinson (BR) buffer of pH 2-11 was investigated by differential pulse cathodic stripping voltammetry (DPCSV) and cyclic voltammetry (CV) at hanging mercury dropping electrode (HMDE). At pH 9-10.5, the DPCSV of SP drug showed two cathodic peaks at -1.15 and -1.38 V at the HMDE vs. Ag/AgCl reference electrode. In the CV, at pH 9-10, the d...