Galvanic corrosion protection by embedded zinc anodes is an accepted technique for the of reinforcing steel in concrete. currents flow between anode and reinforcement due to potential difference that range a few hundred mV. The ion distribution was studied on two reinforced concrete specimens admixed with 3 wt.% chloride/wt. cement galvanically protected surface applied EZ-anode. On both specim...

The precipitation titration of sodium chloride with electrogenerated silver ion was studied. The production of a precipitate of silver chloride had a significant effect on the titration results because the precipitate involved unreacted chloride or unreacted silver ion. The accuracy of the method was investigated by changing the introduction time of a sodium chloride solution to the coulometric...

The rate of hydrochloric acid production by isolated, bullfrog gastric mucosae depends critically on the supply of chloride ion to the serosal surface. Secretion of acid is negligible if chloride is completely replaced by glucuronate and gluconate ion. The experimental evidence indicates that the rate of acid secretion may be regarded as a reaction velocity, depending on chloride concentration ...

The affinities of a series of biologically relevant ions for a hydrated phospholipid membrane were investigated using molecular dynamics simulation. Interactions of molecular ions, such as guanidinium, tetramethylammonium, and thiocyanate with the bilayer were computationally characterized for the first time. Simulations reveal strong ion specificity. On one hand, ions like guanidinium and thio...

Concrete specimens were exposed to weekly cycles of wetting and drying in distilled water and in solutions of sodium chloride, calcium chloride, magnesium chloride, and calcium magnesium acetate with either a 6.04 molal ion concentration, equivalent in ion concentration to a 15% solution of NaCl, or a 1.06 molal ion concentration, equivalent in ion concentration to a 3% solution of NaCl, for pe...

The combined activity of the 1.1.1-cryptand and of a dicopper(II) bistren cryptate complex including chloride makes the Cl(-) ion be continuously and slowly delivered to the solution, without any external intervention. The 1.1.1-cryptand slowly releases OH(-) ions, according to a defined kinetics, and each OH(-) ion displaces a Cl(-) ion from the cryptate. Chloride displacement induces a sharp ...

The chloride-ion concentration dependence of the molecular dimension in the acid-denatured state of equine -lactoglobulin (ELG) was investigated by smallangle X-ray scattering. In the presence of chloride ion, ELG has a globular and compact conformation (the A state). The molecular dimension of ELG increases little with decreasing chloride-ion concentration. A remarkable dependence was observed...

Copper aluminum interconnects are being used in automotive applications for deployment underhood, onengine and on-transmission. Electronics is widely used for enabling safety function including lane departure warning systems, collision avoidance systems, antilock braking systems, and vehicle stability systems. Models for copper interconnect degradation are needed for life prediction modeling to...

The corrosion behavior of oxygen-free copper in anoxic sulfide solutions under nuclear waste disposal conditions was studied using electrochemical impedance spectroscopy (EIS), scanning electron microscopy (SEM) equipped with a focused ion beam (FIB), X-ray photoelectron spectroscopy (XPS) and Micro X-ray diffraction ( XRD). The film growth process and mechanism were elucidated using an Au mark...

The chloride penetration resistance of phosphoaluminate cement (PAC) concrete was investigated in this study. The effects of mixture proportioning parameters, including cement content, water–cement ratio (w/c), and superplasticizer content on chloride ion penetration resistance of PAC concrete were investigated by the rapid chloride migration test (RCM). The result shows that the increase of ce...