A bimetallic core–shell nanostructure is a versatile platform for achieving intriguing optical and catalytic properties. For long time, this has been limited to ones with noble metal cores. Otherwise, galvanic replacement reaction easily occurs, leading hollow nanostructures or completely disintegrated ones. In the past few years, great efforts have devoted preventing reaction, thus creating an...

background: recently, some new nanobiosensors using different nanoparticles or microarray systems for detection of mycotoxins have been designed . however, rapid, sensitive and early detection of aflatoxicosis would be very helpful to distinguish high-risk persons.objectives: we report a highly sensitive competitive immunoassay using magnetic/silica core shell as a signal intensifier for the de...

in this study, a specific ch4 sensor is fabricated based on interdigitated electrode that modified with core-shell of tungsten carbide/tin oxide (wc/sno2) nanoparticles by wet chemical method in different percents of carbon and tungsten. the morphology of wet chemical-synthesized wc/sno2 core-shell was evaluated by different methods such as patterned x-ray diffraction (xrd), and particle size a...

Iron oxide nanoparticles (NPs) with diameters of 16.1, 20.5, and 20.8 nm prepared from iron oleate precursors were coated with poly(maleic acid-alt-1-octadecene) (PMAcOD). The coating procedure exploited hydrophobic interactions of octadecene and oleic acid tails while hydrolysis of maleic anhydride moieties allowed the NP hydrophilicity. The PMAcOD nanostructure in water and the PMAcOD-coated ...

objective(s): this paper describes coating of magnetite nanoparticles (mnps) with amorphous silica shells.   materials and methods: first, magnetite (fe3o4) nps were synthesized by co-precipitation method and then treated with stabilizer molecule of trisodium citrate to enhance their dispersibility. afterwards, coating with silica was carried out via a sol-gel approach in which the electrostati...

in this work, hierarchical wo3 core-shell microspheres were synthesized via a facile template-free precipitation method. gas sensing properties of the synthesized powder to acetone and some other volatile organic compounds were comparatively investigated with commercial wo3 nanoparticles. the synthesized and commercial powders were characterized by x-ray diffraction, scanning electron microscop...

the photocatalytic coatings were prepared via incorporating the modified titania nanoparticles into epoxy-based inorganic-organic hybrid coatings. titania nanoparticles were first synthesized from tetra-n-butyl titanate using sol-gel methods by two different calcination treatments, i.e., in mild condition (80°c) and 500°c. the formed anatase nanoparticles were further modified as titania-silica...

The rational design of highly efficient electrocatalysts for the hydrogen evolution reaction (HER) is of prime importance for establishing renewable and sustainable energy systems. The alkaline HER is particularly challenging as it involves a two-step reaction of water dissociation and hydrogen recombination, for which platinum-based binary catalysts have shown promising activity. In this work,...

The fabrication of highly monodisperse silica coated Au NPs by the microemulsion approach and the selection of the nanostructure morphology have been described. Several experimental conditions, synthetic parameters and post-preparative strategies such as reaction time, precursor concentration, size selection techniques and NP surface treatments have been suitably investigated in order to fabric...

In this paper, the temperature dependence on optical absorption cross section of the core shell bimetallic nanoparticles (NPs) is investigated in quasi static approximation. Temperature dependence of the plasmon resonance is important issue because of recent applications of NPs of noble metal for heat treating of cancer and the computer chips. The effect of temperature on surface plasmon resona...