Crystalline organic solids are ubiquitous as either final products or as intermediates in the specialty chemical, pharmaceutical, and home & personal care industries. Virtually all small molecular weight drugs are isolated as crystalline materials, and over 90% of all pharmaceutical products are formulated in particulate, generally crystalline form. Crystalline chemical intermediates, such as a...

the present work has been performed to eliminate sewage dry sludge of alborze city wastewater treatment plant by using them as fine aggregate in concrete. on this basis, at first the selected dry sludge was analyzed for xrd and xrf for crystalline phases and chemical composition, respectively. the results showed that more than 50% of the sludge is formed of sio2 and it had more than 20% organic...

Nano-structured crystalline tungsten(vi) oxides (WO(3)) were prepared using a colloidal crystal template method; these materials have increased specific surface area compared to crystalline WO(3) prepared without the template, and after platinum loading they show enhanced photocatalytic activity for acetic acid decomposition under visible light.

Highly crystalline TiO(2) nanostructures were prepared through a facile inorganic acid-assisted hydrothermal treatment of hexagonal-structured assemblies of nanocrystalline titiania templated by cetyltrimethylammonium bromide (Hex-ncTiO(2)/CTAB Nanoskeleton) as starting materials. All samples were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The influence...

A novel high-temperature synthesis of niobium oxide nanostructures has been developed through an amorphous intermediate that crystallizes into anisotropic crystalline structures through a complex mechanism of nucleation-dissolution-selective growth induced by seeded growth. The amorphous materials formed by the thermolysis of niobium oleate transformed into crystalline platelets, wires or bundl...

A 46-year-old man presented with a 1-month history of fever. He had undergone peritoneal dialysis for 7 years to treat endstage renal disease and underwent renal transplantation in 2006. For 10 days, he presented with minimal scrotal swelling and discomfort. Ultrasonography showed that both testes were normal in size and had normal echogenicity, but the right epididymis was enlarged, showing mo...

Whispering gallery mode microresonators made from crystalline materials are of great interest for studies of low threshold nonlinear phenomena. Compared to amorphous materials, crystalline structures often exhibit desirable properties such as high indices of refraction, high nonlinearities, and large windows of transparency, making them ideal for use in frequency comb generation, microlasing an...

It is known that the room-temperature plastic deformation of bulk metallic glasses is compromised by strain softening and shear localization, resulting in near-zero tensile ductility. The incorporation of metallic glasses into engineering materials, therefore, is often accompanied by complete brittleness or an apparent loss of useful tensile ductility. Here we report the observation of an excep...

An image plate (IP) detector coupled with high energy synchrotron radiation was used for atomic pair distribution function (PDF) analysis, with high probed momentum transfer Qmax ≤ 28.5 Å−1 from crystalline materials. Materials with different structural complexities were measured to test the validity of the quantitative data analysis. Experimental results are presented here for crystalline Ni, ...

[Chemical reaction: See text] Conjugated, shape-persistent macrocycles based on [3 + 3] Schiff-base condensation are of interest for supramolecular materials. In an effort to develop new discotic liquid crystals based on these compounds, a series of macrocycles with peripheral alkoxy groups of varying length have been prepared. The synthesis and mechanism of formation have been probed by isolat...