Dipolar addition of cyclic azomethine imines with cyclic vinyl sulfones gave rise to functionalized tricycles that exhibited fluxional behavior in solution at room temperature. The scope of the synthetic methodology was explored, and the origin of the fluxional behavior was probed by NMR methods together with DFT calculations. This behavior was ultimately attributed to stereochemical inversion ...

The fatigue behavior of a Ceramic Matrix Composite (CMC) at intermediate temperature under air is investigated. Because of the low density and the high tensile strength of CMC, they offer a good technical solution to design aeronautical structural components. The aim of the present study is to compare the behavior of this composite under static and cyclic loading. Comparison between incremental...

Electrochemical behavior of I-hydroxypyridine-2-thione and its vanadium complex is studied using polarographic techniques. Polarograms of ligand and that of the complex is shown with diffusion characteristics of the waves. Cyclic voltagram of thione is investigated which shows that a reversible oxidation reduction of one electron process is taking place. PKa of the thione is found to be in ...

Cyclic scheduling problems concerning multimodal processes are usually observed in FMSs producing multi-type parts where the Automated Guided Vehicles System (AGVS) plays a role of a material handling system. Schedulability analysis of concurrently flowing cyclic processes (SCCP) executed in these kinds of systems can be considered using a declarative modeling framework. Proposed representation...

We derive upper bounds for the index of cyclicity of a matrix as a function of the size of the matrix. This result can be used in the characterization of the ultimate behavior of the sequence of consecutive powers of a matrix in the max-plus algebra, which has maximum and addition as its basic operations. If the matrix is irreducible then it is well known that the ultimate behavior is cyclic. F...

The redox properties of sulfite ion has been examind using cyclic voltammetry in acetonitrile solvent at the surface of gold, pelatin and glassy carbon electrodes. It has bben found tha, sulfite ion exhibits two electron oxidation peak with EC’ mechanism. A novel chemically modified electrode containing Prussian blue complex and multi wall carbon nanotubes (MWCNs) was achieved on the surface of...

The electrochemical behavior of the cation exchange polymer Nation containing tetrathiafulvalenium (TTF +) on a platinum sub strate is described. The polymer electrode shows cyclic voltammetric behavior similar to that of solid films of TTF on platinum. In 1.0M KBr the oxidized form of the electroactive molecules in the polymer (TTF § forms nonstoichiometric complexes with Br-. The peak potenti...

finite affine groups are given by groups of translations and di-lations on finite cyclic groups. for cyclic groups of prime orderwe develop a time-scale (wavelet) analysis and show that for alarge class of non-zero window signals/vectors, the generatedfull cyclic wavelet system constitutes a frame whose canonicaldual is a cyclic wavelet frame.

Although fatigue damage in bone induced by cyclic loading has been recognized as a problem of clinical significance, few fracture mechanics based studies have investigated how incipient cracks grow by fatigue in this material. In the present study, in vitro cyclic fatigue experiments were performed in order to quantify fatigue-crack growth behavior in human cortical bone. Crack-growth rates spa...

In order to improve the oxidation resistance of ferritic stainless steel, it is possible to deposit a protective coating on steel substrate. In this research through the usage of pack cementation method a coating of titanium was applied on the surface of AISI 430 stainless steel. Scanning Electron-Microscopy (SEM), Energy- Dispersive X-ray spectrometry (EDAX) and X-ray diffraction (XRD) were us...