In order to apply ionic liquids (ILs) to the separation of rare earth metals, liquid-liquid extraction of a series of rare earth elements into the ILs was investigated mainly using 1-octyl-3-methylimidazolium bis(trifluoromethyl sulfonyl) imide, [C8mim][Tf2N], with N,N-dioctyldiglycol amic acid (DODGAA) as the extractant. A higher selectivity was exhibited for the heavier rare earth elements as...

Spent Nickel cadmium batteries are classified as hazardous waste due to the presence of toxic cadmium in high concentration. Recycling of metal value by environmentally friendly process is the best option to obtain economical advantage and prevent environmental pollution. In the present investigation, a metal separation scheme is proposed for recovery of cadmium, nickel and cobalt from the leac...

A simple and low-cost apparatus for continuous and efficient liquid-liquid extraction, which does not need continual mechanical forces (stirring, shaking, etc.) other than solution sending, has newly been developed. This apparatus, named "emulsion flow" extractor, is composed of a column part where an emulsified state fluid flow (emulsion flow) is generated by spraying micrometer-sized droplets...

The mass transfer performance of a pulsed disc and doughnut column for extraction of samarium and gadolinium from aqueous nitrate solution with D2EHPA was investigated. The effects of operating parameters such as pulsation intensity, continuous and dispersed phase velocities on column performance were investigated. The axial dispersion model was used to obtain the overall mass transfer coef...

In this work, an adsorbent was prepared based on the attachment of organophosphorus acid extractants, namely, D2EHPA, CYANEX 272, and CYANEX 301, to the surface of superparamagnetic magnetite (Fe3O4) nanoparticles. The synthesized nanoparticles were coated with oleic acid, first by a chemisorption mechanism and later by the respective extractant via physical adsorption. The obtained core-shell ...