The enantioselective Michael addition using water as both nucleophile and solvent has to date proved beyond the ability of synthetic chemists. Herein, the direct, enantioselective Michael addition of water in water to prepare important β-hydroxy carbonyl compounds using whole cells of Rhodococcus strains is described. Good yields and excellent enantioselectivities were achieved with this method...

Mangrove forest trees grow in severe conditions such as diurnal submersion and high salinity surface and subsurface waters. This study focuses on two species on Mayotte Island, i.e. Ceriops tagal and Rhizophora mucronata, living in the middle range of the coastal mangrove. The seedlings of these trees were planted in a tropical greenhouse with an original pump system built to reproduce the natu...

The microscopic distribution and dynamic state of water in native potato, maize and pea starch granules are investigated with NMR relaxometry and diffusometry. Besides extra-granular water, three water populations can be identified inside native potato starch granules. These are assigned to water in the amorphous growth rings; water in the semi-crystalline lamellae and “channel water”, which is...

Sediments from 28 saline and hypersaline (salinity 13.6–149.2) ponds on Christmas Island (Kiritimati), in the Central tropical Pacific Ocean, were investigated for the effect of salinity on the D/H ratios of lipid biomarkers. Hydrogen isotope ratios (expressed as dD values) of total lipid extracts, and individual hydrocarbons heptadecane, heptadecene, octadecane, octadecene, diploptene, and phy...

Fourier transform spectrometer data of heavy water vapor were obtained at resolutions of 0.01 and 0.02 cm-1. The spectra were analyzed to obtain line center frequencies and line strengths of HD16O from 4719 to 5843 cm-1. The analysis included 1700 assigned lines of the (011)-(000), (200)-(000), (120)-(000), and (021)-(010) bands. This is the first report of assignments in the weak (120)-(000) b...

Numerous self-assembling molecules have been synthesized aiming at mimicking both the structural and dynamic properties found in living systems. Here we show the application of hydrogen/deuterium exchange (HDX) mass spectrometry (MS) to unravel the nanoscale organization and the structural dynamics of synthetic supramolecular polymers in water. We select benzene-1,3,5-tricarboxamide (BTA) deriv...

Modern concepts of nuclear reactors cooled with supercritical water are presented together with a short history. The supercritical water-cooled CANDU ((CANada Deuterium Uranium) is a registered trademark of AECL) reactor concept is fully discussed. Also, thermophysical properties at critical and supercritical pressures as well as heat transfer and hydraulic resistance at these conditions are pr...

In an earlier paper in this series observations were reported on the rate at which glycogen in the liver and carcass of rats was being replaced by freshly synthesized glycogen while the animals were maintained at constant weight (1). The rats used in those experiments were fed a diet containing 60 per cent of glucose. From determination of the rate at which deuterium was incorporated into glyco...

Soil and epikarst play an important role in the hydrological cycle in karst regions. This paper focuses on investigating the seasonal recharge and mean residence time (MRT) of soil water and epikarst water in a small karst catchment of southwest China. The deuterium contents in precipitation, creek, soil baseflow (direct recharge of the saturated soil water to the stream), epikarst spring, and ...