In this work, a methodological route to find fluorescent radiometric OFF–ON type configuration of rhodamine B with diethylenetriamine dissolved in ethanol for the detection Cd2+ on surface basil roots is presented. The proposed has very fast response time and highly selective sensitive linear range between 10 1000 μg/L. Furthermore, obtained quantum efficiency 0.63 projects as strategic option ...

BACKGROUND The coordination chemistry of cadmium(II) with diamine ligands is of particular interest. The most common structure around cadmium(II) center in their complexes is tetrahedral, that is due the octet rule obeyed. Nevertheless, five and six-coordinated complexes are also well known. Now a day, many cadmium(II) complexes with chelate ligands were synthesized for their structural or appl...

Solution equilibrium studies on Cu(2+)-L(1)-L(2) ternary systems have been performed by pH-potentiometry, UV-Vis spectrophotometry and EPR methods {where L(1) corresponds to a polyamine such as ethylenediamine (en), diethylenetriamine (dien), N,N,N',N',N″-pentamethyldiethylenetriamine (Me(5)dien)} and L(2) denotes 2-aminoethylphosphonic acid (β-alaninephosphonic acid)}. The results suggest the ...

Although protein tyrosine kinases (PTKs) signaling has been implicated in the late phase of ischemic preconditioning (PC), it is unknown whether PTK signaling is necessary for the development of nitric oxide (NO) donor-induced late PC. Thus conscious rabbits underwent a sequence of six 4-min coronary occlusion (O)/4-min reperfusion (R) cycles followed by a 5-h recovery period of reperfusion for...

An efficient fluorescent Al(3+) receptor, N-(2-hydroxy-1-naphthalene)-N'-(2-(2-hydroxy-1-naphthalene)amino-ethyl)-ethane-1,2-diamine (L) has been synthesized by the condensation reaction between 2-hydroxy naphthaldehyde and diethylenetriamine. High selectivity and affinity of L towards Al(3+) in ethanol (EtOH) as well as in HEPES buffer at pH 7.4, makes it suitable to detect intracellular Al(3+...

A simple, effective and green bottom-up method for the synthesis of highly fluorescent N doped graphene oxide quantum dots (GOQDs) and polymer-like quantum dots (PQDs) was developed on the basis of rapid one-step microwave assisted pyrolysis of citric acid (CA) and diethylenetriamine (DETA) in different reaction solvents. Both one-photon-induced and two-photon-induced photoluminescence (PL) pro...

Two water-soluble N-containing additives without sulfur and phosphorus, hexanamide with tetraethylenepentamine (EEHA) benzotriazole amide diethylenetriamine (BTAA), were synthesized used as in the oil-in-water emulsion to investigate effect of amino ring on tribological properties emulsion. The results showed that EEHA/BTAA exhibited wear resistance under all tested conditions. This may be attr...

The adsorption of CO2 on amine modified periodic mesoporous organosilicas (PMOs) has been investigated. An ethenylene-bridged PMO is modified with a wide range of diamines and polyamines. A variety of dangling N-containing functionalities, i.e., diaminobutane, diaminohexane, diaminododecane, diethylenetriamine and tetraethylenepentamine, as nucleophiles in a substitution reaction is used. The C...

Gd-diethylenetriamine pentaacetic acid-bismethylamide, Gd(DTPA-BMA), is shown to be a reagent suitable for the identification of protein surfaces. Compared to the conventionally used spin-label TEMPOL, Gd(DTPA-BMA) is a stronger relaxation agent, requiring lesser concentrations to achieve the same paramagnetic relaxation enhancement of solvent-exposed protein protons. It is also less hydrophobi...

T1-, T2-, and diffusion-weighted MRI was used to determine whether repetitive transcranial magnetic stimulation (rTMS) affects the blood-brain barrier or induces localized brain edema. In 11 healthy individuals, 1,200 to 3,800 stimuli were applied over the visual cortex of one hemisphere in series of 5-, 10-, or 20-Hz stimulus trains. MRI performed 6 minutes to 6 hours after rTMS did not show p...