In summary, a novel structure of MOF based on 1,4–di ([2,2':6',2''terpyridin] -4'-yl)benzene and 1,4-naphthalenedicarboxylic acid has been constructed through hydrothermal reaction. The Ni-MOF displays one dimensional zigzag chain, which connect each other by hydrogen bonding to form three supramolecule with large channels. conjugated systems the terpyridin benzene ligands enhance chain rigidit...

A two-dimensional (2D) Zn(II) metal-organic framework with flexible aryl ether linkers and water molecules exposed to the pores was prepared. The supramolecular three-dimensional (3D) network is generated by the presence of extensive π-π contacts, which could be responsible for gas uptake. The water molecules and oxygen atoms from the flexible linkers create a polar environment within the integ...

sieve trays are widely used in the gas- liquid contactors such as distillation and absorption towers. in this article, a three-dimensional, two phase cfd model using euler-euler framework was developed to simulate a distillation tower with two sieve trays. hydrodynamic simulation of air and water system in different rates of gas phase was carried out and velocity distribution parameters, clear ...