Methods are presented for the separation of chlorins from marine particles and sediments for nitrogen and carbon isotopic analysis. Carbon and nitrogen purities of 91 and 96%, respectively, were obtained for particulate chlorins, with recoveries of 88%. Sedimentary chlorins were obtained with carbon and nitrogen purities of 88 and 89%, respectively, and recoveries of 18%. The reproducibility of...

a simple, rapid and sensitive solvent assisted-dispersive solid phase extraction method was developed for the extraction of iron(ii) prior to its spectrophotometric determination. the fe(ii) reacted with 2,4,6-tris(2-pyridyl)-1,3,5-triazine, neutralized with sodium dodecyl sulfate and extracted onto the fine particles of benzophenone which were formed upon rapid injection of a mixture of benzop...

This paper presents an experimental study on the dissolution kinetics and solvent extraction of total gold from Ijero-ekiti (Nigeria) gold ore deposit by hydrochloric acid leaching followed by extraction with Tributylphosphate (TBP) in kerosene. The leaching investigation showed that the gold ore dissolution in HCl solution increases with increasing acid concentration, temperature and with decr...

in this work, an environmentally friendly sample pre-treatment method, ultrasound assisted surfactant enhanced emulsification microextraction (uaseme) followed with spectrofluorimetry was performed for determination of oxadiazon residues in water samples. after the determination of the most suitable extraction solvent and its volume, other parameters such as type and concentration of surfactant...

pectin is used as gelatinizing agent in food industry. in this study pectin was extracted from five commercial sugar beet varieties namely: doroty, rasul, 7112, br1 and ic using pre-hydrolysis technique. experiments were conducted using factorial design to verify the effect of temperature, time, percentage of hcl and water requirements on the extraction rate of pectin. the qualitative factors o...

Direct analysis of samples, regardless their origin, is desirable although for the majority of cases unfeasible on account of the complexity of the sample matrix, inadequate concentration of the target analytes, or even incompatibility with the detector. In these cases, a sample pretreatment step is required for interference removal and analytes separation/preconcentration. Despite valuable adv...

This paper proposes improved guidelines for dissolved organic matter (DOM) isolation by solid phase extraction (SPE) with a styrene-divinylbenzene copolymer (PPL) sorbent, which has become an established method for the isolation of DOM from natural waters, because of its ease of application and appreciable carbon recovery. Suwannee River water was selected to systematically study the effects of...

a pressurized fluid extraction (pfe) method for the extraction of pistachio oil was developed using a modified supercritical fluid extractor. the supercritical fluid extraction apparatus was modified to be able to pump liquid solvent and co2 into the extraction vessel alternatively. the experimental results showed that the extraction yield was independent of the extraction pressure. it was also...