in this work, polypyrrole/ceo2 nanocomposite (nc) was synthesized in the presence of methylorange as a reactive self-degraded soft template. the field emission scanning electron microscopy(fesem) images indicate that the ceo2 nps have a nucleus effect and cause a homogenous ppycore–shell type morphology with an encapsulation of the ceo2 core by the ppy shell. the effect ofnc on acrylic waterbor...

A method based on Electrochemical Impedance Spectroscopy (EIS) for the diagnosis of prosthesis osseointegration was proposed by the Authors in previous works [1]-[2]. In this paper, the design, the implementation, and the metrological characterization of a microcontroller-based prototype conceived as a stand alone instrument to be used for in-vivo clinical applications are presented. The prelim...

Electrochemical impedance spectroscopy (EIS) was used to detect stress corrosion cracking (SCC) in stainless steel 304 alloy exposed to an aqueous environment at 120 °C. Stainless steel 304 alloy as u-bend was tested in the solution that contains 40 weight percent of magnesium chloride. U-bended samples were prepared according to ASTM G30. EIS measurements were always performed simultaneously o...

The hydrogen evolution reaction (HER) on Ni57.3Co42.7 alloy and its main components, polycrystalline nickel and cobalt was investigated in 1.0 mol L–1 NaOH solution at 20 °C using cyclic voltammetry, pseudo-steady-state linear polarization and electrochemical impedance spectroscopy methods. The purpose of investigation was to evaluate the effect of cobalt on the intrinsic catalytic activity of ...

The paper aims on the investigations of corrosion processes of three different porcelain fused to metal dental crowns with CoCrMo frameworks. The three crowns, with different exposed metal surfaces, were investigated using electrochemical impedance spectroscopy (EIS), through 168 hours of experiment. The data were analyzed and the influence of corrosion processes was shown after the crowns were...

The effects of H2SO4 concentration on the electrochemical behaviour of passive films formed on AISI 304 stainless steel were investigated using by potentiodynamic polarization, Mott–Schottky analysis and electrochemical impedance spectroscopy (EIS). Potentiodynamic polarization indicated that the corrosion potentials were found to shift towards negative direction with an increase in solution co...

Knowledge of solvent effects on the redox properties of Murexide (Mu) is important for understanding its role as an electron acceptor in analytical and inorganic chemistry. In the present study, an investigation of the electrochemical behavior of the compound by both Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS) in both aqueous and non-aqueous solutions was undertaken...

Diffusion–convection impedance for a micro-band electrode placed in Poiseuille flow was studied experimentally under microfluidic conditions. Electrochemical spectroscopy (EIS) experiments performed with fast electrochemical system show perfect agreement previously published quantitative analytical expression the low frequency domain.

The electrochemical behavior of the oxide layers on two metal-metal glassy alloys, Fe78Co9Cr10Mo2Al1 (VX9)and Fe49Co49V2 (VX50) (at.%), were studied using electrochemical techniques including electrochemical frequency modulation (EFM), electrochemical impedance spectroscopy (EIS) and cyclic polarization (CP) measurements. The morphology and composition of the alloy surfaces were investigated us...

Materials to devices: Electrochemical impedance spectroscopy (EIS) is a powerful technique used in electrochemical research interrogate materials, full cell devices and packs. This review summarizes the latest developments EIS for sulfur, oxide polymer solid-state electrolytes blocking electrode, symmetric configurations, with an outlook on how its applicability this field can be improved.