Ethylene carbonate (EC) is the archetype solvent in Li-ion batteries. Still, questions remain regarding numerous possible reaction pathways of EC. Although pathway involving direct EC reduction and SEI formation most commonly discussed, ring-opening often observed, but seldomly addressed, especially with respect to formation. By applying Online Electrochemical Mass Spectrometry, on carbon found...

The addition of 2% vinyl ethylene carbonate (VEC) into LiPF6/EC + DMC electrolyte can significantly improve the cyclic performance of a LiNi0.8Co0.2O2/Li cell at elevated temperatures such as 50 °C. In situ electrochemical mass spectrometry (EMS) was used to investigate the gas evolution spectroscopy in the cell during a charge/discharge process with and without VEC additive. Fourier transform ...

Biodiesel is nowadays added in 5–10% v/v to diesel, and its production involves the parallel creation of a vast glycerol amount as by-product. Despite many applications, there surplus (Gly) that has boosted search for new applications this compound, now transformed into an industrial synthesis intermediate or platform chemical. Its transcarbonation type reaction occurs under mild conditions, us...

Ultraviolet and heat-curable polyurethane acrylate prepolymers were synthesized from 4,4’-diphenyl methane diisocyanate, polyethylene adipate diol, polyhexamethylene carbonate diol, polycaprolactone diol and 1,6hexamethylene diamine , acrylic acid. Effects of nature of the soft segments on the physical properties were investigated. It was found that the thermal stability increased from polycarb...

The major plant growth regulator ethephon degrades to ethylene and phosphate in aqueous solutions and plants and is spontaneously activated to a butyrylcholinesterase (BChE) inhibitor in alkaline solutions and animal tissues. In the present (31)P NMR kinetic study of the reactions of ethephon in pH 7.4 carbonate buffer, we observed a transient peak at 28.11 ppm. The time course for the appearan...

Submit Manuscript | http://medcraveonline.com Abbreviations: GPC: Gel Permeation Chromatography; FTIR: Fourier Transform Infra Red; XRD: X Ray Diffraction; HRTEM: High Resolution Transmission Electron Microscopy; TGA: Thermo Gravimetric Analysis; IEC 60520: International Electronic Commission Number 60520; BS 7655: British Standard Number 7655; PMMA: Poly Methyl Methacrylate; PC: Poly Carbonate...

The composition of the lithium cation (Li(+)) solvation shell in mixed linear and cyclic carbonate-based electrolytes has been re-examined using Born-Oppenheimer molecular dynamics (BOMD) as a function of salt concentration and cluster calculations with ethylene carbonate:dimethyl carbonate (EC:DMC)-LiPF6 as a model system. A coordination preference for EC over DMC to a Li(+) was found at low s...