This study aiming to determine the optimal conditions degrade an organophosphate pesticide diazinon (DZN) at low levels concentrations (μg.mL−1) and identify by-products generated. The degradation processes utilized were Fenton photo-Fenton. iron concentration [Fe2+], hydrogen peroxide [H2O2], solution pH are investigated parameters. Doehlert three-parameter experimental design was applied mode...

OBJECTIVES Biebersteinia multifida is a common herb known in Iran. Its roots have been used locally in folk medicine of western region of Iran in the treatment of many diseases. The antioxidant activity and its inhibition of erythrocyte hemolysis were investigated. MATERIAL AND METHODS 1,1-diphenyl-2-picryl hydrazyl radical (DPPH), nitric oxide and hydrogen peroxide scavenging activities, Fe2...

OBJECTIVES The Ferula genus (Umbelliferae) is a rich source of gum-resin and is much utilized in folklore medicine. This study is designed to examine antioxidant and antihaemolytic activities of Ferula foetida regel flower, stem and leaf extracts. MATERIALS AND METHODS 1,1-Diphenyl-2-picryl hydrazyl radical (DPPH), nitric oxide and H2O2 scavenging activities, Fe2+ chelating ability, reducing ...

Using ESR spin-trapping techniques with 5,5-dimethyl-1-pyrroline-N-oxide (DMPO), we confirmed the 1:1 stoichiometry for the formation of hydroxyl radicals with Fe2+ in the Fenton reaction under experimental conditions wherein [H2O2] is 90 microM and [Fe2+] is very low, 1 microM or less. The stoichiometry decreased markedly as the Fe2+ concentration was increased. The efficiency of hydroxyl radi...

In this work, the synchronous removal of Cr(VI) and bisphenol A (BPA) in a heterogeneous Fenton process with sulfidated nanoscale zero-valent iron (S-nZVI) as reductant catalyst was systematically evaluated. Compared to other systems including S-nZVI or H2O2 alone, simultaneous BPA degradation could be achieved S-nZVI/H2O2 system at an optimum pH 3. It was, interestingly, found that 7.8% 98.2% ...

Oxidation of pyrite (FeS2) plays a significant role in the redox cycling of iron and sulfur on Earth and is the primary cause of acid mine drainage (AMD). It has been established that this process involves multi-step electron-transfer reactions between surface defects and adsorbed O2 and H2O, releasing sulfoxy species (e.g., S2O32-, SO42-) and ferrous iron (Fe2+) to the solution and also produc...

Fenton or photocatalytic degradations of organic contaminants are recognized as promising approaches to address the increasing environmental pollution issues. Herein, we develop effective synergistic catalysis reaction and photocatalysis based on a loofah sponge-like Fe2Ox/C nanocomposite, which exhibits excellent nitrobenzene degradation property. It is noted that Fe2O3 nanoparticles with surf...

the saline tannery wastewater also contains the high concentration of organic materials and various chemical compounds like lime, sodium sulfite, sulfate ammonium, sodium chloride, disinfections, vegetable tannins, salts of chromium and chloride. in recent years different applications of advanced oxidation processes (aops) are applied to remove organic loading (cod) from wastewater. advanced ox...