Introduction: Metakaolin (MK) is used as supplementary cementitious material to reduce the CO 2 footprint of Portland cements. However, early hydration cement (OPC) often retarded due its use. The present work investigates mechanisms this retardation. Focus laid on interaction MK with main clinker phase C 3 S (Ca SiO 5 , pure form alite) that known govern kinetics OPC. Methods: Hydration reacti...