Journal of the American Chemical Society is published by the American Chemical Society. 1155 Sixteenth Street N.W., Washington, DC 20036 A systematically designed homogeneous oscillating reaction: the arsenite-iodate-chlorite system Patrick De Kepper, Irving R. Epstein, and Kenneth Kustin J. Am. Chem. Soc., 1981, 103 (8), 2133-2134• DOI: 10.1021/ja00398a061 • Publication Date (Web): 01 May 2002...

Over 100 μW of continuous-wave tunable ultraviolet radiation at 370 nm is generated by the sum-frequency mixing of radiation from two extended-cavity laser diodes having powers of 60 mW at 822 nm and 8 mW at 671 nm in a lithium iodate crystal. The crystal is placed in an external cavity that enhances the powers of two fundamental beams simultaneously by approximately 40. This light source is su...

A sensitive spectrophotometric method for the determination of iodine species like iodide, iodine, iodate and periodate is described. The method involves the oxidation of iodide to ICl(2)(-) in the presence of iodate and chloride in acidic medium. The formed ICl(2)(-) bleaches the dye methyl red. The decrease in the intensity of the colour of the dye is measured at 520 nm. Beer's law is obeyed ...

The objective of the study was to determine seasonal variation in the concentration of tannins in wild bush tea (Athrixia phylicoides L.) leaves. The BuOH-HCl_Fe reagent was used to analyze condensed tannins, whereas hydrolysable tannin was analyzed using potassium iodate. The absorbance was measured using a spectrophotometer. Significant seasonal variations in both condensed and hydrolysable t...

Autocatalytic reaction between reacted and unreacted species may propagate as solitary waves, namely, at a constant front velocity and with a stationary concentration profile, resulting from a balance between molecular diffusion and chemical reaction. The effect of advective flow on the autocatalytic reaction between iodate and arsenous acid in cylindrical tubes and Hele-Shaw cells is analyzed ...

By numerically simulating the Bray-Liebhafsky (BL) reaction (the hydrogen peroxide decomposition in the presence of hydrogen and iodate ions) in a continuously fed well stirred tank reactor (CSTR), we find "structured" types of chaos emerging in regular order with respect to flow rate as the control parameter. These chaotic "structures" appear between each two successive periodic states, and ha...

Two front instabilities in a reaction-diffusion system are shown to lead to the formation of complex patterns. The first is an instability to transverse modulations that drives the formation of labyrinthine patterns. The second is a nonequilibrium Ising-Bloch (NIB) bifurcation that renders a stationary planar front unstable and gives rise to a pair of counterpropagating fronts. Near the NIB bif...

In 1950, a quarter of a century after his first-ever nonlinear optical experiment when intensity-dependent absorption was observed in uranium-doped glass, Sergey Vavilov predicted that birefringence, dichroism and polarization rotatory power should be dependent on light intensity. It required the invention of the laser to observe the barely detectable effect of light intensity on the polarizati...

A flow-injection method has been developed for the determination of total sulphite in wine samples. After hydrolysis of bound sulphite, sulphur dioxide is separated from the matrix by means of an in-line gas diffusion module. For detection indirect amperometry is used, with iodine as oxidizing reagent. The iodine can be generated in-line by merging and mixing iodate and iodide solutions, or alt...

The results of a study and application of leucocrystal violet for the determination of antimony in parts per million levels is described here. The proposed method is based on the reaction of antimony(III) with acidified potassium iodate to liberate iodine. The liberated iodine selectively oxidizes leucocrystal violet to crystal violet dye. The formed dye shows maximum absorbance at 590 nm. The ...