BACKGROUND Obesity is currently epidemic in many countries worldwide and is strongly related to diabetes and cardiovascular disease. Mass spectrometry, in particular matrix-assisted laser desorption/ionization time of flight (MALDI-TOF) is currently used for detecting different pattern of expressed protein. This study investigated the differences in low molecular weight (LMW) peptide profiles b...

The chemical composition of airborne particulate matter (PM) was studied at a coastal region near De Haan, Belgium, during a winter-spring and a summer campaign in 2006. The major ionic components of size-segregated PM, i.e. NH(4)(+), Na(+), K(+), Mg(2+), Ca(2+), Cl(-), NO(3)(-), and SO(4)(2-), and related gaseous pollutants (SO(2), NO(2), NH(3), HNO(2), and HNO(3)) were monitored on a daily ba...

The successful formulation of particulate dispersions is often hindered by the presence of charged species dissolved in solution. If present at high enough concentrations, these species can reduce the screening length between particles to near zero, allowing rapid coagulation and destabilization. The addition of a mixture of ionic and nonionic surfactants has been shown in a previous publicatio...

The dynamic motion of ions in electrolyte solutions and its effect on recombination was investigated by the heterodyne transient grating method in addition to transient absorption and transient photocurrent methods in dye sensitized solar cells. Realignment of ionic species at the electrode/electrolyte interface was observed after the electron injection in TiO2 on the order of μs. The process w...

Experimental and simulation results of solvation dynamics in ionic liquids have so far been explained in terms of translational motion of the ions constituting the ionic liquids under investigation. A recent theoretical study [Kashyap & Biswas, J Phys Chem B, 114 (2010) 254] has indicated that while translational motion of the constituent ions is indeed responsible for Stokes’ shift dynamics of...

The aim of this study was to investigate the influence of pH, buffer species and ionic strength on the release mechanism of chlorpheniramine maleate (CPM) from matrix tablets containing chitosan and xanthan gum prepared by a hot-melt extrusion process. Drug release from hot-melt extruded (HME) tablets containing either chitosan or xanthan gum was pH and buffer species dependent and the release ...

A brief summary of selected pioneering and mechanistic contributions in the field of carbon-carbon cross-coupling reactions with palladium nanoparticles (Pd-NPs) in ionic liquids (ILs) is presented. Five exemplary model systems using the Pd-NPs/ILs approach are presented: Heck, Suzuki, Stille, Sonogashira and Ullmann reactions which all have in common the use of ionic liquids as reaction media ...

background: cold-induced aggregation micro extraction based (ciame) based on ionic liquid was used as a rapid and simple method for determination trace amounts of cadmium and lead in milk powder by analysis with flame atomic absorption spectrometry (faas). methods: sample solution containing of cd2+ and pb2+ in dynamic range, phosphate buffer (ph = 9, 3 ml), diethyl dithiocarbamate (complexing ...

Ionic-liquid ion sources produce beams of charged particles through evaporation and acceleration ions droplets from the surface an ionic liquid. The composition emitted beam can impact performance for various applications such as focused microfabrication space propulsion. Numerical inference is considered quantification ionic-liquid source determining current fraction different species along wi...

Bare-metal based REDOX and conductivity sensors that are used to detect ionic species in solution by measuring the electrochemical cell current as the voltage is scanned. The simplicity and robustness of these sensors allows their use in the analysis of ionic species found in natural and drinking water. The measurements include 1) conductivity measurements which provide a gross indication of th...