Evidence for the self-aggregation of 10(S)-chlorophyll a (= chlorophyll a') in nonpolar solvents has been obtained by means of absorption spectroscopy in the visible and infrared regions. The visible absorption spectrum of chlorophyll a' exhibits a shoulder at 680 nm in aliphatic hydrocar­ bon solvents and the infrared spectrum measured in carbon tetrachloride contains an “aggrega­ tion peak” a...

5-Hydroxymethylfurfural (HMF) is a biobased platform chemical that can be valorized into spectrum of valuable products. In this report, supported Ir, Ir–Co, Ir–Ni, and Ir–Ru catalysts were investigated for purpose. Only hydrogenation HMF to 2,5-bis-(hydroxymethyl)furan (BHMF) occurred over all catalysts. The effect the second metal (Co, Ni, Ru) on Ir/SiO2 was reflected by kinetic constants bein...

Infrared (IR) spectroscopic imaging of human liver tissue slices has been used to identify and characterize liver tumors. Liver tissue, containing a liver metastasis of breast origin (mucinous carcinoma), was surgically removed from a consenting patient and frozen without formalin fixation or dehydration procedures, so that lipids and water remained in the tissues. A set of IR metrics (ratios o...

We report double-resonant IR/UV ion-dip spectroscopy of neutral gramicidin peptides in the gas phase. The IR spectra of gramicidin A and C, recorded in both the 1000 cm(-1) to 1800 cm(-1) and the 2700 to 3750 cm(-1) region, allow structural analysis. By studying this broad IR range, various local intramolecular interactions are probed, and complementary IR modes can be accessed. Ab initio quant...

Continuum observations at radio, millimetre, infrared and soft X-ray energies are presented for a sample of 22 quasars, consisting of flat and steep spectrum radio loud, radio intermediate and radio quiet objects. The primary observational distinctions, among the different kinds of quasars in the radio and IR energy domains are studied using large observational datasets provided by ISOPHOT on b...

We investigate the sensitivity of femtosecond Fourier transform two-dimensional infrared spectroscopy to protein secondary structure with a study of antiparallel beta-sheets. The results show that 2D IR spectroscopy is more sensitive to structural differences between proteins than traditional infrared spectroscopy, providing an observable that allows comparison to quantitative models of protein...

The gas-phase infrared spectra of radical cationic and protonated corannulene were recorded by infrared multiple-photon dissociation (IRMPD) spectroscopy using the IR free electron laser for infrared experiments. Electrospray ionization was used to generate protonated corannulene and an IRMPD spectrum was recorded in a Fourier-transform ion cyclotron resonance mass spectrometer monitoring H-los...

We construct boundary states representing D-strings in AdS3. These wrap twisted conjugacy classes of SL(2, IR), and the boundary states are therefore based on continuous representations only. We check Cardy’s condition and find a consistent open string spectrum. The open string spectrum on all the D-branes is the same.

We present 1–5 lm IR reflectance spectra of CO2 clathrate hydrates acquired under temperature and pressure conditions representative of the icy moons’ surfaces. The IR reflectance spectrum of the CO2 clathrate hydrates is similar to the water ice IR reflectance spectrum except for two main absorption bands corresponding to the CO2 guest molecule at 2.71 and 4.28 lm (3693 and 2334 cm!1). The spe...

Modeling Multi-User Interference (MUI) is crucial in the design of wireless networks. In the case of Impulse Radio (IR)Ultra Wide Band (UWB) networks, most of the adopted models are inspired by the legacy of the reference literature on spread spectrum communications, and do not address specific features for IR systems, where spectrum spreading is basically obtained by the radiation of very shor...