BACKGROUND A new organodithiophosphorus derivative, namely O-(1,3-Bispiperidino-2-propyl)-4-methoxy phenyldithiophosphonate, was synthesized and then the kinetic behavior of the transport process as a function of concentration, temperature, stirring rate and solvents was investigated. RESULTS The compound 1 was characterized by elemental analysis, IR, 1H and 31P NMR spectroscopies. The transp...

Many features of granular media can be modelled as a fluid of hard spheres with inelastic collisions. Under rapid flow conditions, the macroscopic behavior of grains can be described through hydrodynamic equations. At lowdensity, a fundamental basis for the derivation of the hydrodynamic equations and explicit expressions for the transport coefficients appearing in them is provided by the Boltz...

Background: In the present study, the photocatalytic (TiO2/UV) batch process has been used for the methyl orange (MO) degradation. Methods: In the catalyst range from 0.25 to 1.5 g/L, the optimum concentration of TiO2 was found to be 0.5 g/L. The kinetic behavior of MO degradation has been evaluated using the non-linear form of pseudo-first order and pseudo-second order models. Results: The g...

While the stoichiometry of metabolism is probably the best studied cellular level, the dynamics in metabolism can still not be well described, predicted and, thus, engineered. Unknowns in the metabolic flux behavior arise from kinetic interactions, especially allosteric control mechanisms. While the stoichiometry of enzymes is preserved in vitro, their activity and kinetic behavior differs from...

Phase behavior of distearoylphosphatidylethanolamine dispersed in excess glycerol has been examined by differential scanning calorimetry. Transformation from lamellar-gel to lamellar crystalline phase was found to take place at temperatures near 74.9 degrees C upon cooling and near 76.3 degrees C during heating scans. The transition can also be observed under isothermal conditions at temperatur...

Hydrothermal synthesis of nickel-chitosan hybrid  has  been accomplished using Ni(CH3COO)2,4H2O, chitosan and water as starting material, template and solvent respectively, followed by calcination at 800 and 900˚C to provide nanoporous NiO800  and NiO900. The solid products were characterized by X-ray diffraction (XRD), nitrogen adsorption-desorption, scanning electron microscopy (SEM) and Four...

This paper presents the influence of Hybrane H 1500 as a hyperbranched polymer on kinetic parameters of dyeing compounded fiber grade PET polyethylene terephthalate at boil temperature. C.I. Disperse Red 324 as a disperse dye was used for dyeing compounded fiber grade PET. The result was compared with corresponding properties of virgin PET. The dyeing rate constants and diffusion coefficients a...

We consider the problem of estimating the probability density of the “anchor point” (residence, place of work, etc.) of a criminal offender given a set of observed spatial locations of crimes committed by the offender. Starting from kinetic models of criminal motion and target selection, we derive the probability density of anchor points using the Fokker-Planck equation and Bayes’ Theorem. Here...

The steady-state and rapid kinetic properties of xanthine oxidase containing a series of FAD analogs of varying reduction potential have been investigated. From steady-state analysis, Vmax is found to exhibit a sigmoidal dependence on the flavin midpoint potential in the homologous series. This dependence is accurately described by a model in which the rate of catalysis is attenuated by the amo...

We are interested in flows on general networks and derive a kinetic equation describing general production, social or transportation networks. Corresponding macroscopic transport equations for large time and homogenized behavior are obtained and studied numerically. This work continues a recent discussion [20] and provides additionally explicit equilibrium solutions, second–order macroscopic ap...