The influence of operation temperature, inlet gas composition, current density and the anode thickness on methane steam reforming reaction over nickel yttria-stabilized zirconia anodes was experimentally studied in solid oxide fuel cells. experimental results were analyzed using data fitting Power-Law Langmuir–Hinshelwood kinetic models. Similar trends dependence partial pressures observed both...

By use of operando spectroscopies under cycling reaction conditions, water is shown to hamper the redox dynamics realistic palladium oxide nanoparticles dispersed onto alumina and hydrophobic zeolite supports thereby lowering activity for total oxidation methane. Water adsorption forms hydroxyl ad-species that block methane oxygen dissociation seem prevent lattice take part in oxidation. The ma...

Abstract Zn-doped NaA molecular sieves were prepared by hydrothermal method using zinc nitrate, sodium metaaluminate, silica sol, etc. as raw materials. The samples characterized XRD, SEM, FT-IR, etc., 300W xenon lamp the light source. Rhodamine B (RhB) was used target degradant for photocatalytic experiments its activity. results showed that ion doping increased number of active sites on sieve...

kinetic modeling is an important issue, whose objective is the accurate determination of the rates of various reactions taking place in a reacting system. this issue is a pivotal element in the process design and development particularly for novel processes which are based on reactions taking place between various types of species. the fischer tropsch (ft) reactions have been used as the kineti...

ethylene was polymerized in slurry phase over a ticl4/mg(oc2h5)2 catalyst activated by al(c2h5)3. it was shown experimentally that mass transfer resistance has no effect on polymerization kinetics. after estimation ofthe active site concentration by inhibition method with carbon monoxide, the effects of polymerization temperature, monomer and cocatalyst  oncentrations and hydrogen were investig...

acetylene dose due to the high supply of hydrogen. Moreover, methane should not be formed, since there should not be any dissociation of acetylene on the surface. Figure 11 shows the result of an experiment in which the surface was precovered with a monolayer of hydrogen. The first dose of acetylene (0.2 X 1015 molecules of C2H2 cm-2) leads to an enormous increase in the hydrogen pressure and t...

Glycerol hydrogenolysis represents one of the most promising technologies for future bio-refineries. In this context, kinetic modeling provides key quantitative assessment significance various reactions process development. However, as present, there are only limited studies on detailed glycerol conversion to 1,2-propanediol, ethylene glycol and other alcoholic products. work, a comprehensive s...

Hierarchical BEA zeolite was prepared through desilication or followed by acid treatment. The catalytic performance of samples evaluated using Friedel-Crafts acylations with two substrates different molecular sizes, furan (5.7 Å) and benzofuran (6.9 Å), in the presence acetic anhydride as acylating agent. application simplified Langmuir-Hinshelwood kinetic model showed that size substrate leads...