The heterobimetallic peralkylated complexes [Ln(AlR4)2]n (Ln = Sm, Yb; R = Me, Et) were synthesized by a silylamide elimination route from Ln[N(SiMe3)2]2(THF)2 and an excess of AlR3. The solid-state structure of [Sm(AlEt4)2]n is isomorphous to that of the ytterbium derivative. Polymeric [Yb(AlMe4)2]n was examined by 1H and 13C MAS NMR spectroscopy revealing the presence of distinct bridging met...

A new variant of the ARCH class of models for forecasting conditional variance, to be called the Generalized AutoRegressive Conditional Heteroskedasticity Parkinson Range (GARCH-PARK-R) Model, is proposed. The GARCH-PARK-R model, utilizing the extreme values, is a good alternative to the Realized Volatility that requires a large amount of intra-daily data, which remain relatively costly and are...

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

We study the provision of public goods when all agents have complete information and can write binding agreements. This framework is in deliberate contrast to a traditional view of the free-rider problem based on hidden information or voluntary provision. We focus on coalition formation as a potential source of inefficiency. To this end, we develop a notion of an equilibrium coalition structure...

We investigated a series of nickel-based oxyarsenides LnNiAsO (Ln=La, Ce, Pr, Nd, Sm) compounds. CeNiAsO undergoes two successive anti-ferromagnetic transitions at TN1=9.3 K and TN2=7.3 K; SmNiAsO becomes an anti-ferromagnet below TN≃3.5 K; NdNiAsO keeps paramagnetic down to 2 K but orders anti-ferromagnetically below TN≃1.3 K. Superconductivity was observed only in Kramers non-magnetic LaNiAsO...

The compounds BaLn(2)Se(4) (Ln = rare-earth metal = lanthanide = Er, Tm and Yb), namely barium di(erbium/thulium/ytterbium) tetraselenide, crystallize in the orthorhombic space group Pnma in the CaFe(2)O(4) structure type. In this structure type, all atoms possess m symmetry. The Ln atoms are octahedrally coordinated by six Se atoms. A three-dimensional channel structure is formed by the corner...

This paper seeks to establish within a formal framework how Coloured Petri Nets can be enhanced to produce Object Petri Nets. It does so by defining a number of intermediate Petri Net formalisms and identifying the features introduced at each step of the development. Object Petri Nets support a complete integration of object-oriented concepts into Petri Nets, including inheritance and the assoc...

Let {Xi, i = 1, 2, . . .} be i.i.d. standard gaussian variables. Let Sn = X1 + . . . + Xn be the sequence of partial sums and Ln = max 0≤i<j≤n Sj − Si √ j − i . We show that the distribution of Ln, appropriately normalized, converges as n → ∞ to the Gumbel distribution. In some sense, the the random variable Ln, being the maximum of n(n+1)/2 dependent standard gaussian variables, behaves like t...

The ChucK programming language lacks straightforward mechanisms for extension beyond its built-in programming and processing facilities. Chugens address this issue by allowing programmers to implement new unit generators in ChucK code in realtime. Chubgraphs also allow new unit generators to be built in ChucK, by defining specific arrangements of existing unit generators. ChuGins allow a wide a...

Velocity and acceleration characteristics provide valuable information about dynamic control of accommodation. We investigated velocity and acceleration of disaccommodation (near-far focusing) from three starting positions. Peak velocity and peak acceleration of disaccommodation increased with the proximity of starting position however for a given starting position they were invariant of respon...