Arapid, highly sensitive and efficient flotation/magnetic stirring-assisted liquid-liquid microextraction combined with flame atomic absorption spectrometry has been proposed for the preconcentration and quantitative analysis of trace amounts of cadmium (II) in the presence of sodium diethyldithiocarbamateas complexingagent. Parameters including sample pH, concentration of the complexingagent, ...

Homogeneous liquidliquid microextraction; Flotation assistance; Diazinon; Water samples ABSTRACT: In the present study a sensitive method for extraction of diazinon in water samples was developed using homogeneous liquid-liquid microextraction via flotation assistance (HLLMEFA). Toluene at microliter volume level was used as extraction solvent. The main advantages of method are high enrichment ...

An air–assisted liquid–liquid microextraction method for the extraction and preconcentration of trace amounts of some synthetic phenolic antioxidants in biological fluids followed by their determination by gas chromatography–flame ionization detection has been reported. In this method the target analytes are extracted into a few microliters of carbon tetrachloride (extraction solvent) from an a...

magnetic nanoparticles attracted a great deal of attention in the medical applications due to their unique properties. the most exceptional property of magnetic particles is their response to a magnetic force, and this property has been utilized in applications such as drug targeting, bioseparation, contrast agents in magnetic resonance imaging (mri) and heating mediators for cancer therapy. in...

in this study, we combined ionic liquid-based dispersive liquid liquid micro extraction (il-dllme) with faas for determining the palladium in different real samples at the trace level. 1-hexyl-3-methylimidazolium hexafluorophosphate [hmim][pf6] ionic liquid and 1-(2-pyridylazo) 2-naphthol (pan), were chosen as the extraction solvent and the chelating agent, respectively. the hydrophobic pd–pan ...

Migration of chemicals from plastic containers into drinks and liquids containing them, is supposed to be a hazardous phenomenon and results in many health problems. Sample preparation is of great importance due to trace amounts analysis of these compounds. In this research, dispersive liquid–liquid microextraction is applied for the extraction and preconcentration of the migrated compounds pri...

the lamiaceae family consists of a broad spectrum of medicinal plants involving marrubium l. genus. regarding the diverse pharmaceutical uses of the plants belonging to this genus, they can be considered as proper alternatives for chemical drugs having harmful effects. the present work aims to identify and characterize chemical compositions of the essential oils and volatiles from the aerial pa...

This paper presents a novel and simple cleanup procedure based on hollow fiber liquid-phase microextraction (HF-LPME) for the determination of trace estradiol in environmental. Estradiol was extracted from a 140-mL water sample (the donor phase) into the pores of the hollow fiber wall organic solvent, then into the organic solvent (the acceptor phase) in the lumen of the hollow fiber. Afterward...

A novel and low solvent consumption method for the sensitive determination of fungicide residues in wine samples is proposed. Analytes were extracted by dispersive liquid-liquid microextraction (DLLME) and further determined by gas chromatography-mass spectrometry (GC-MS). Under optimized conditions, a binary mixture of acetone and 1-undecanol (0.5 and 0.05 mL, respectively) was used to extract...