Heusler type Ni-Mn-Ga ferromagnetic shape memory alloys can demonstrate excellent magnetic shape memory effect in single crystals. However, such effect in polycrystalline alloys is greatly weakened due to the random distribution of crystallographic orientation. Microstructure optimization and texture control are of great significance and challenge to improve the functional behaviors of polycrys...

statement of the problem: one disadvantage of cement-retained crowns is the lack of predictable irretrievability. this problem can be overcome through designing a screw access hole in the metal substructure of cement-retained restoration and using porcelain stain to define this area. purpose: this study aimed to evaluate the influence of existence of screw access hole on porcelain fracture resi...

OBJECTIVES The use of ceramic femoral heads in total hip arthroplasty (THA) has increased due to their proven low bearing wear characteristics. Ceramic femoral heads are also thought to reduce wear and corrosion at the head-stem junction with titanium (Ti) stems when compared with metal heads. We sought to evaluate taper damage of ceramic compared with metal heads when paired with cobalt chromi...

The friction and wear behaviour of ZrO*-Y203, Zr02-Y203--Ce02 and ZrQ--A1203 composite ceramics against hardened steel AISI-52100 were investigated using a pin on plate configuration under reciprocating motion. The reproducibility of the results was examined in this configuration. Wear characteristics were separated into system and material contributions. Under the conditions used, all the cera...

Arenetricarbonyl metal complexes ([-phM(CO)3-] and [-biphM(CO)3-]; ph = phenylene, biph = biphenylene, M = Mo, Cr) constructed within Zr-based MOFs act as highly active and selective catalysts for epoxidation of cyclooctene. Catalytic activities of these complexes are enhanced with increasing the pore sizes of Zr-based MOFs.

A novel organic polymer composite for the encapsulation of metal catalysts and applications to synthesis are described here.

Butane-2,3-dione was activated towards nucleophilic addition of enecarbamates by a series of metal triflate complexes of a C2-symmetric diamine to give stereogenic, aldol-like, t-alcohols, a novel nickel(II) triflate complex was identified as a good catalyst for this asymmetric transformation, and an aquo nickel(II) complex was identified by XRD techniques.

The effects of femtosecond laser machining on surface characteristics and subsurface microstructure of a Nitinol alloy were studied. The femtosecond laser machining produced an average surface roughness of 0.2 μm. A re-deposited layer of 7 μm and a hardened layer of 70 μm were also resulted from the machining.

We observed that diffuse interfaces sharpen rather than broaden in completely miscible ideal binary systems. This is shown in situ during heat treatments at gradually increasing temperatures by scattering of synchrotron radiation in coherent Mo/V multilayers containing initially diffuse interfaces. This effect provides a useful tool for the improvement of interfaces and offers a way to fabricat...

High-entropy alloys are an intriguing new class of metallic materials that derive their properties from being multi-element systems that can crystallize as a single phase, despite containing high concentrations of five or more elements with different crystal structures. Here we examine an equiatomic medium-entropy alloy containing only three elements, CrCoNi, as a single-phase face-centred cubi...