Block copolymers represent an exciting class of complex materials as they self-assemble into highly regular structures of nanoscopic dimensions. When prepared as thin films, such structures can be used for a variety of applications including lithographic masks or nanoporous membranes. Reported here are nanostructures in thin films of structurally analogous polybutadiene-block-poly(2-vinyl pyrid...

Methods: Light-hardened poly-methyl-methacrylate, poly-hydroxyl-ethyl-methacrylate, and calcium hydroxide plus polyanhydride (PPCH+PA) composite graft), PPCH graft alone, PA graft alone, were compared to each other and to a no graft control group. All mandibular premolar teeth were extracted; a total of 48 implants were placed into sockets of the mesial roots in three minipigs. Crestal areas an...

The main objective was to investigate the effects of different polishing techniques on the color stability of provisional prosthetic materials upon exposure to different staining agents by mimicking the oral environment in vitro. Fifty-six cylindrical specimens were prepared for each type of material: bis-acryl and light-polymerized composite resins, and methyl methacrylate- and ethyl methacryl...

A resin monomer-soluble polyrotaxane (PRX) crosslinker with cleavable end groups was synthesized to develop degradable photosetting composite resins. The PRX containing 50 α-cyclodextrins (α-CDs) with disulfide end groups was initially modified with n-butylamine to obtain a resin monomer-soluble PRX. The PRX containing 13 n-butyl groups per α-CD molecule was completely soluble in conventional r...

objectives: several studies have assessed the characteristics and properties of silorane-based composites and adhesive systems. considering the extensive application of tooth-whitening agents, possible deteriorative effects of tooth bleaching agents on these restorative materials must be studied. the aim of this study was to evaluate the effect of an in-office carbamide peroxide-based tooth ble...

objectives: repairing composite restorations is a challenging procedure especially when two different types of composites are used. this study aimed to compare the repair strength of silorane-based composite (sc) (filtek p90) with that of preheated sc, methacrylate composite (mc)(z250), flowable mc (filtek supreme plus) and different adhesive/composite combinations. materials and methods : eigh...

objectives: this study aimed to assess the effects of two energy drinks on color change (∆e) of two methacrylate-based and a silorane-based composite resin after one week and one month. materials and methods: thirty cubic samples were fabricated from filtek p90, filtek z250 and filtek z350xt composite resins. all the specimens were stored in distilled water at 37°c for 24 hours. baseline color ...

Successful regeneration of biological tissues in vitro requires the utilization of three-dimensional (3D) scaffolds that provide a near natural microenvironment for progenitor cells to grow, interact, replicate, and differentiate to form target tissues. In this work, a rapid aqueous photo-polymerization route was developed toward the fabrication of a variety of polymer hydrogel 3D inverted coll...

We present a new 4D printing approach that can create high resolution (up to a few microns), multimaterial shape memory polymer (SMP) architectures. The approach is based on high resolution projection microstereolithography (PμSL) and uses a family of photo-curable methacrylate based copolymer networks. We designed the constituents and compositions to exhibit desired thermomechanical behavior (...