Synlett 2002, No. 12, Print: 02 12 2002. Art Id.1437-2096,E;2002,0,12,2023,2026,ftx,en;G27602ST.pdf. © Georg Thieme Verlag Stuttgart · New York ISSN 0936-5214 Abstract: Microwave irradiation is used to accelerate Pauson– Khand reactions. The conditions for the Pauson–Khand reaction, catalytic in Co2(CO)8 under microwave irradiation, were optimized. It is possible to obtain various types of [2+2...

We have previously reported a new synthesis of amides from esters and amines under microwave irradiation, offering much higher yields than those achieved with conventional heating [1]. We have now extended these studies to the ring closure of neat iminoesters I2, I3 and I4-I6 to give five- and six-membered ring lactams L5, L6 and larger lactams L7-L9 (where I means imine and L means lactam), re...

Silver nanoparticles were prepared by microwave irradiation of silver nitrate solution with carboxymethyl chitosan as reducing agent and a stabilizer. The optical properties, morphology and structure were characterized using UV–Visible spectrophotometer, transmission electron microscope (TEM) and X-ray diffraction (XRD). Appearance of surface plasmon band at 413 nm indicated the formation of si...

An efficient method for synthesis of 1Acetal diethyl-1H-indole-3-carbaldehyde by combinaison of 1H-indole-3-carbaldehyde and bromoacetal diethyl using Natural phosphate doped with K2CO3 (NP/K2CO3) is described .The reactions promoted by microwave irradiation are advantageous in many ways because of short reaction time, and solvent free reaction conditions . Several reactions of synthetic import...

In this study, a microwave/UV/TiO(2)/ozone/H(2)O(2) hybrid process system, in which various techniques that have been used for water treatment are combined, is evaluated to develop an advanced technology to treat non-biodegradable water pollutants efficiently. In particular, the objective of this study is to develop a novel advanced oxidation process that overcomes the limitations of existing s...

A simple, low reflection, and highly-efficient pilot-plant scale microwave irradiation reactor for woody biomass pretreatment was fabricated. Pretreatment is an essential process for effective bioethanol production. The fabricated reactor consists of 8 microwave irradiators which are attached to a metal pipe. The woody biomass mixture which contains water and organic acid flows through the meta...

Computational calculations represent a very useful tool to study separately the occurrence of thermal and non-thermal effects of microwave irradiation through the determination of the thermodynamic and kinetic parameters of the reaction. In this paper, we approach the computational study of two previously reported cycloaddition reactions. All of the outcomes indicate the presence of a thermal e...

An improved synthesis of multifunctionalized pyrrolo[2,3,4-kl]acridine derivatives with different substituted patterns using silica sulfuric acid (SSA) as a heterogeneous catalyst under microwave irradiation conditions was developed. The reaction could be conducted by using readily available and inexpensive substrates within short periods of 12-15 min. under microwave irradiation. Compared with...

In this work, the effects of preparation methods such as CE oven, microwave irradiation, and ultrasound on the morphology, particle size and crystallinity of MIL-53(Fe) are firstly investigated. Furthermore, the methods are utilized to prepare Pt NPs@MIL-53(Fe). As a result, well-defined Pt NPs@MIL-53(Fe) prepared by microwave irradiation exhibits uniformed morphology, hig...

The application of the [Pd{C6H3(CH2CH2NH2)-4-OMe-5-κ2-C,N}(μ-Br)]2 complex of 2-methoxyphenethylamine in the Heck coupling reaction was considered under both conventional and microwave irradiation conditions, and their results were compared. This complex is an efficient, stable and non-sensit...