The influence of polymer surface-protein binding affinity on protein ion signals in matrix-assisted laser desorption/ionization (MALDI) mass spectrometry is examined. The surfaces of poly(vinylidene fluoride) and poly(ethylene terephthalate) polymer substrates are modified by pulsed rf plasma deposition of allylamine. By varying the on/off duty cycle of the pulsed rf plasma, the polymer substra...

The kinetics of structural relaxation and crystallization of poly(ethylene terephthalate) (PET) is studied. It is demonstrated that the activation energy depends strongly on fictive temperature Tf . The dependence of the glass transition temperature Tg on the heating rate q + is investigated for samples that were previously cooled down at a rate q = 12.5 K/min. Angell et al [1] compare the ther...

Over 359 million tons of plastics were produced worldwide in 2018, with significant growth expected the near future, resulting global challenge end-of-life management. The recent identification enzymes that degrade previously considered non-biodegradable opens up opportunities to steer plastic recycling industry into realm biotechnology. Here, sequential conversion post-consumer polyethylene te...

Self-reinforced poly(ethylene terephthalate) (PET) composites prepared by using a modified film-stacking technique were examined in this study. The starting materials included a high tenacity PET yarn (reinforcement) and a low melting temperature biodegradable polyester resin (matrix), both of which differ in their melting temperatures with a value of 56°C. This experiment produced composite sh...

The dielectric loss spectra of a series of copolyesters of poly(ethylene terephthalate) and poly(ethylene isophthalate) have been measured as a function of temperature in a broad frequency range (10(-1)-10(9) Hz). By these measurements, the merging of the two relevant relaxations alpha and beta has been studied. The beta processes exhibit a complex temperature dependence, showing a clear Arrhen...