nanocrystalline particles of barium hexaferrite has been prepared by the sol–gel auto- combustion method using iron and barium nitrate with a ba:fe molar ratio of 1:10. the effect of fuel such as citric acid and aspartic acid was investigated on the structure and magnetic properties of nanoparticles. the results revealed that the formation of barium hexaferritefine particles is influenced by mo...

this study aims to investigate the capability of forming itraconazole containing niosomes with span 60 and brij 58 as non-ionic surfactants. lower cost and higher stability makes niosomes a more suitable choice in comparison with liposomes.the capability to form vesicles as an itraconazole delivery system and the influence of different factors such as type of surfactant and molar ratio of chole...

in this work, we report synthesis and characterization of copper nanoparticles in polymer matrix by wet-chemical reduction method using ascorbic acid as reducing agent, copper (ii) sulfate as metal precursor and polyvinylpyrrolidone k-30 (pvp k-30) as surfactant agent. the reaction was carried out in a high-speed stirring mixture at room temperature under nitrogen atmosphere. characterization o...

according to the unique properties and many applications of nano gold powder, it was prepared from an acid leaching tail solution. the low value residual gold ions existed in acid leaching tail solution in mouteh gold mine in iran with fellow heavy metals as pollutants (fe2+, cu2+, and zn2+). preparation of nano gold particles is achieved by two steps: first, by addition of ammonia as separatio...

Canola oil was transesterified using a 1 : 1 molar mixture of methanol and ethanol (M/E) with potassium hydroxide (KOH) catalyst. The effects of catalyst concentration (0.5–1.5 wt-%), molar ratio of M/E to canola oil (3 : 1 to 20 : 1) and reaction temperature (25–75 7C) on the percentage yield measured after 2.5 and 5.0 min were optimized using a central composite design. A maximum percentage y...

The synthesis of a supramolecular ionic network, its physical properties, and the use of this network property to form macroscopic porphyrin fibers are described. These ionic networks are compared to ionic liquids. Current ionic liquid compositions have a charge and molar ratio of 1:1 where an anionic species is matched with a cationic species; however, alteration of this molar ratio while main...

In this study the influence of dicarboxy acetone (DCA), as an oxidation product of sodium citrate, was evaluated by ‘reversed Turkevich’ method in this study. Gold nanoparticles (GNPs) were synthesized systematically at various sodium citrate to HAuCl4 molar ratio and temperature. TheseThe GNPs were characterized by UV-vis spectroscopy, DLS and TEM techniques. The results showed that by reversi...

The molar flow rate of carbon has been selected as the processing parameter for comparison for several reasons. The heterogeneous feedstock (air/oxygen and solid material such as biomass) of most gasifiers permits a wide range of total mass feed rate depending on parameters such as the C/O ratio of the solid, the S/C ratio of the gasifier feed, and equivalence ratio of the gasifier. However, th...

in this paper, modeling and optimization of fischer-tropsch synthesis is considered in a fixed-bed catalytic reactor using an industrial fe-cu-k catalyst. a one dimensional pseudo-homogenous plug flow model without axial dispersion is developed for converting syngas to heavy hydrocarbons. the effects of temperature, pressure, h2 to co ratio in feed stream, and co molar flow on the mass flow rat...

this study presents the synthesis of polyvinyl acetate (pvac) by solution polymerization and its partial hydrolysis to polyvinyl alcohol (pva) using alkaline alcoholysis. the influence of the molar ratio of hydrolysis catalyst (naoh) to pvac and the time and temperature of the saponification reaction on the degree of hydrolysis and molecular weight of the pva were investigated using response su...