The expression of the moa locus, which encodes enzymes required for molybdopterin biosynthesis, is enhanced under anaerobiosis but repressed when the bacterium is able to synthesize active molybdenum cofactor. In addition, moa expression exhibits a strong requirement for molybdate. The molybdate enhancement of moa transcription is fully dependent upon the molybdate-binding protein, ModE, which ...

Phosphate (PO 4 3? ) is an important nutrient for phytoplankton growth and at high loadings can result in water quality deteriorations. Autonomous PO measurements are required monitoring purposes, best achieved using sensitive, portable low-cost techniques. Here we describe a new electrochemical sensor detection seawater. The quantification of typically depends on the reaction between molybdate...

Mercury methylation and demethylation rates were measured in periphyton biofilms growing on submerged plants from a shallow fluvial lake located along the St. Lawrence River (Quebec, Canada). Incubations were performed in situ within macrophytes beds using low-level spikes of (199)HgO and Me(200)Hg stable isotopes as tracers. To determine which microbial guilds are playing a role in these proce...

Zusammenfassung DEHP und DINP sind Primärweichmacher, die in vielen Weich-PVC-Artikeln wie Beißringen für Kleinkinder eingesetzt werden. Die Ultraschallbad-Extraktion scheint gut geeignet zur Bestimmung der Migration von Phthalaten aus Kunststoff-Gegenständen und liefert Werte, wie sie auch beim Saugen mit Testpersonen erhalten worden waren. Die höheren Migrationsraten, die beim Kauen der Kunst...

Experiments were conducted to study the ability of surfactant-modified clinoptilolite for molybdate adsorption from aqueous solutions. Clinoptilolite was treated with some cationic surfactants. Adsorption of surfactants on zeolite surface was confirmed by chemical analysis, IR (Infra-Red Spectroscopy), DTG (Derivative Thermogravimetry) and SEM (Scanning Electron Microscopy) techniques. The modi...

During the screening for Rhodobacter capsulatus mutants defective in xanthine degradation, one Tn5 mutant which was able to grow with xanthine as a sole nitrogen source only in the presence of high molybdate concentrations (1 mM), a phenotype resembling Escherichia coli mogA mutants, was identified. Unexpectedly, the corresponding Tn5 insertion was located within the moeA gene. Partial DNA sequ...

The relative stability of hydrogen-bonded of Molybdate-Phosphonic Acid (MPA) complex (1:2) ingas phase has been carried out using Density Functional Theory (DFT) methods. The methods are usedfor calculations are B3LYP, BP86 and B3PW91 that have been studied in two series of basis sets: D95**and 6-31+G(d,p) for hydrogen and oxygen atoms; LANL2DZ for Mo and Phosphorus. Predictedhydrogen-bond geom...