Edge-carboxylated graphite (ECG) was produced by grinding pristine graphite in a planetary ball-mill machine. Transmission electron microscope was used to confirm the layers of graphene in ECG. The elemental analyses showed that the oxygen contents are different between ECG samples. The vibrational analysis of singleand five-layered graphene was conducted using finite element method within ANSY...

this paper discusses the use of box behnken design (bbd) approach to plan the experiments for turning the yield of cvd, thickness and layer number of graphene sheets with an overall objective of optimizing the process to provide higher graphene production volume, fewer layers and thinness structure of graphene. bbd is having the maximum efficiency for an experiment involving four factors such a...

We present a general study on a high performance supercapacitor based on intercalated reduced graphene oxide with carbon black nanoparticles. Graphene oxide sheets were synthesized by oxidation and exfoliation of natural graphite and were reduced using hydroiodic acid in the presence of carbon black nanoparticles. Graphene paper was fabricated by one-step procedure via simultaneous reducing and...

A green approach for the preparation of water-dispersible functionalized graphene via one-step electrochemical exfoliation of graphite using 7,7,8,8-tetracyanoquinodimethane (TCNQ) anions as surface modifiers and electrolytes was described. TCNQ is an organic charge-transfer complex with electron accepting and noteworthy electrical properties. The exfoliation of graphite to a few-layer graphene...

In this article, element free Galerkin method is used for static analysis of thin micro/nanoscale plates based on the nonlocal plate theory. The problem is solved for the plates with arbitrary boundary conditions. Since shape functions of the element free Galerkin method do not satisfy the Kronecker’s delta property, the penalty method is used to impose the essential boundary conditions. Discre...

The nonlocal nonlinear buckling of a double layer graphene sheet (DLGS) covered by zinc oxide (ZnO) piezoelectric layers is investigated in this study. The surrounding circumstances of the system are considered as a Pasternak foundation including spring constants and a shear layer. Graphene sheets are subjected to longitudinal magnetic field and biaxial forces. On the other hand, the ZnO piezoe...

Graphene is two-dimensional nanomaterial consisting of a single layer of sp2 network of carbon atoms (Fig. 1a)1. While the thickness of a graphene sheet is on the order of a single atomic unit, its lateral dimension can approach up to tens of microns. Graphene and its derivatives such as graphene oxide (GO) (Fig. 1b), and reduced graphene oxide (r-GO, a.k.a. chemically modified graphene) (Fig. ...

The toughness and coefficient of thermal expansion of a series of functionalized graphene sheet epoxy nanocomposites are investigated. Functionalized graphene sheets are produced by splitting graphite oxide into single graphene sheets through a rapid thermal expansion process. These graphene sheets contain ~ 10% oxygen due to the presence of hydroxide, epoxide, and carboxyl functional groups wh...

Solution-processable thin layer graphene is an intriguing nanomaterial with tremendous potential for electronic applications. In this work, we demonstrate that electrochemical exfoliation of graphite furnishes graphene sheets of high quality. The electrochemically exfoliated graphene (EG) contains a high yield (>80%) of one- to three-layer graphene flakes with high C/O ratio of 12.3 and low she...

The interaction of H atoms with the curved concentric graphene walls of a multiwall carbon nanotube and the stacked planar graphene sheets of graphite was investigated using a combination of high resolution transmission electron microscopy HRTEM in conjunction with electron energy-loss and Raman spectroscopies. Continuous cylindrical graphene walls of a nanotube are etched and amorphized by the...